銆€銆€纭唶(Thiol)鏄竴绉嶅寘鍚矾鍩哄畼鑳藉洟鐨勫寲鍚堢墿銆傜~閱囩殑鑻辨枃鍗曡瘝thiol涔熸潵婧愪簬鈥渢hion鈥濆拰鈥渁lcohol鈥濅袱涓瘝鐨勭粍鍚堬紝鍏朵腑绗竴涓儴鍒嗘潵婧愪簬甯岃厞璇殑胃蔚?慰谓 (theion)锛屽嵆鈥渟ulfur鈥濄€傜~閱囧湪鑻辨枃涓湁鏃朵篃琚О涓衡€渕ercaptan鈥濓紝杩欎釜鍗曡瘝鏄?832骞寸敱涓归害鍝ユ湰鍝堟牴澶у鐨勫▉寤?#8226;鍏嬮噷鏂墭寮?#8226;钄℃柉(William Christopher Zeise)鏁欐巿鍦ㄥ彂鐜扮~閱囨椂鎵€缁欎簣鐨勫懡鍚嶏紝杩欎釜璇嶆潵婧愪簬鎷変竵璇嶇殑mercurium capt膩ns(鑻辨枃锛歝apturing mercury锛屼腑鏂囷細鎹曡幏姹?锛屽洜涓虹~閱囩洂鍜屾睘鍖栧悎鐗╃殑缁撳悎闈炲父寮恒€侟/span>
銆€銆€寰堝纭唶锛岀壒鍒槸浣庡垎瀛愰噺鐨勭~閱囬兘鍏锋湁寮虹儓銆佷护浜虹敓鍘岀殑绫讳技澶ц挏鍛抽亾銆傝嚟榧墍鍠峰皠鐨勮嚟鍛冲氨鏄綆鍒嗗瓙閲忕殑纭唶鍙婂叾琛嶇敓鐗┿€傝繖浜涗綆鍒嗗瓙閲忕殑纭唶鍖栧悎鐗╋紝鍚噺鍗充娇浠呮湁鍗佷嚎鍒嗕箣鍗?10ppb)锛屼汉绫婚蓟瀛愰兘鍙互闂诲埌銆?937骞?鏈?8鏃ョ編鍥藉痉鍏嬭惃鏂窞鏂颁鸡鏁︿腑瀛?New London School)鍙戠敓浜嗛€犳垚295鍚嶅鐢熷拰鏁欏笀姝讳骸鐨勭編鍥藉巻鍙蹭笂鏈€涓ラ噸瀛︽牎鎯ㄦ鐨勫ぉ鐒舵皵澶х垎鐐稿嚑鍛ㄤ箣鍚庯紝绔嬫硶褰撳眬寮哄埗瑕佹眰鍦ㄥぉ鐒舵皵(鏈韩鏄棤鑹叉棤鍛崇殑)涓坊鍔犵~閱囨潵纭繚娉勬紡浼氳鍙婃椂鎰熺煡銆傚綋鐒讹紝骞朵笉鏄墍鏈夌殑纭唶閮芥湁杩欑浠や汉涓嶅揩鐨勫懗閬撱€侟/span>
銆€銆€鐢ㄤ簬娑傛枡宸ヤ笟涓殑纭唶锛岄€氬父鍙互鍒嗕负閱氱被缁撴瀯鍜岄叝绫荤粨鏋勩€傚叾涓啔绫荤粨鏋勶紝鍖呮嫭涓滀附鐨凲E-340M锛孉DEKA鐨凟H-310锛孋ognis鐨凜apcure3-800鍜屼笁鑿卞寲瀛︾殑ERCure QX11绛夈€侟/span>
銆€銆€閰被缁撴瀯鐨勭~閱囬€氬父鏉ユ簮浜庡矾鍩虹晶閰镐簬澶氬厓閱囦箣闂寸殑閰寲鍙嶅簲鑰屽緱鍒般€傚寘鎷牶鍖栧銆佹穩鍖栧鍜孊RUNOBOCK鐨凾MPMP銆丳ETMP绛夛紝浠ュ強鏄拰鐢靛伐鐨凨arenzMTBD1銆丳E1绛夈€侟/span>
銆€銆€鑷敱鍩哄瀷鐨勫厜鍥哄寲鍙嶅簲閮芥槸閫氳繃鍏夊紩鍙戝墏浜х敓鑷敱鍩猴紝鐒跺悗閫氳繃鑷敱鍩鸿繘琛岄摼澧為暱鍙嶅簲浣垮垎瀛愰噺寰楀埌涓嶆柇澧炲姞锛屾暣涓綋绯讳粠鑰屽緱鍒板浐鍖栥€備絾鏄哀姘旂殑瀛樺湪浼氬拰鑷敱鍩哄舰鎴愭椿鎬ф瀬浣庣殑杩囨哀鑷敱鍩猴紝浠庤€屼娇寰楁暣涓厜鍥哄寲鍙嶅簲澶уぇ鍑忕紦锛岀敋鑷充腑姝€€侟/span>
銆€銆€浠庝笂涓笘绾?0骞翠唬寮€濮嬶紝浜轰滑灏卞彂鐜颁簡纭唶鍦ㄥ厜鍥哄寲鏍戣剛閰嶆柟鍙嶅簲涓浜庢哀姘旂殑鎶戝埗浣滅敤锛屼篃灏辨槸鍏嬫湇姘ч樆鑱氭晥搴斻€傚叾鎵€鍙戞尌鐨勪綔鐢ㄥ拰鍏舵祿搴︺€佸畼鑳藉害銆佷笝鐑吀閰绫讳互鍙婂厜寮曞彂鍓傜绫绘湁瀵嗗垏鐨勫叧绯汇€傜~閱囨墍甯︽潵鐨勮嚜鐢卞熀閫愭鑱氬悎鍙嶅簲閫氬父琚畾涔変负纭唶鐑?thiol-ene)鍙嶅簲銆傜浉搴斿弽搴旀満鐞嗗涓嬪浘鎵€绀恒€侟br/>
寮曞彂
閾惧闀军/span>
姘ф皵瀛樺湪鎯呭喌涓婞/span>
銆€銆€鍦ㄥ厜鍥哄寲閰嶆柟涓紝鍗充娇鍦ㄤ笉娣诲姞鍏夊紩鍙戝墏鐨勬儏鍐典笅锛岀~閱囩殑鍔犲叆涔熷彲浠ュ紩鍙戠儻鐑冪被鍖栧悎鐗╃殑鍏夎仛鍚堝弽搴旓紝鍏夊紩鍙戝墏鐨勫姞鍏ュ彲浠ヨ繘涓€姝ュ姞蹇厜鍥哄寲鍙嶅簲鐨勮繘琛屻€備笂鍥炬墍琛ㄧず鐨勬槸鐢辩~閱囧紩鍙戠殑鍏夎仛鍚堝弽搴旓紝鑰屽綋鍦ㄤ笝鐑吀閰強鍏夊紩鍙戝墏鍚屾椂瀛樺湪鐨勬儏鍐典笅锛屽弽搴旂殑鏈虹悊浼氬彉寰楁洿鍔犲鏉傘€侰ramer鍜孊owman绛変汉灏嗙~閱囧拰涓欑儻閰搁叝鍏卞悓鍔犲叆鍒伴厤鏂逛腑锛屽彂鐜颁笝鐑吀閰殑杞寲鐜囦负纭唶鐨勪袱鍊嶃€傚疄闄呴厤鏂逛腑閫氬父浼氫娇鐢ㄥ畼鑳藉害鏇撮珮鐨勭~閱囷紝鍥犱负杩欎笉浠呭鍔犱簡鍙嶅簲鐨勫畼鑳藉洟锛屽悓鏃朵篃鏇村揩鍦板鍔犲弽搴斾綋绯荤殑绮樺害浠庤€屼娇寰楁哀姘旂殑鎵╂暎鍙樻參銆侟/span>
銆€銆€鏈坊鍔犲厜寮曞彂鍓傛潯浠朵笅纭唶-HDDA锛岀~閱?HDDMA鍜岀~閱?浜屼箼鐑熀鑻綋绯荤殑杞崲鐜嘃/span>
銆€銆€a)纭唶()鍜屼笝鐑吀閰畼鑳藉洟()1:1褰撻噺娣峰悎鐗╋紝鍙婄~閱?)鍜屼笝鐑吀閰畼鑳藉洟()1:4褰撻噺娣峰悎鐗╋紱
銆€銆€b)纭唶()鍜岀敳鍩轰笝鐑吀閰畼鑳藉洟()1:1褰撻噺娣峰悎鐗╋紝鍙婄~閱?)鍜岀敳鍩轰笝鐑吀閰畼鑳藉洟()1:4褰撻噺娣峰悎鐗╋紱
銆€銆€c)纭唶()鍜屼箼鐑熀鑻畼鑳藉洟()1:1褰撻噺娣峰悎鐗╋紝鍙婄~閱?)鍜屼箼鐑熀鑻畼鑳藉洟()3:7褰撻噺娣峰悎鐗┿€傛牱鍝侀噰鐢?20-500nm娉㈤暱绱鐓у皠锛屽己搴?5mW/cm2
銆€銆€纭唶铏界劧鍙互鏈夋晥鍦板厠鏈嶆哀闃昏仛锛屼絾鏄皵鍛充互鍙婂偍瀛樼ǔ瀹氭€ц繖涓や釜闂涓€鐩存槸鍏跺緱鍒版洿鍔犲箍闃斿簲鐢ㄧ殑涓昏闅滅銆傛皵鍛充富瑕佹潵婧愪簬纭唶閰按瑙f墍浜х敓鐨勫皬鍒嗗瓙(褰撶劧绾害涓嶉珮鐨勭~閱囦篃浼氭畫鐣欐湁姘斿懗鐨勫皬鍒嗗瓙)锛岃€屽偍瀛樼ǔ瀹氭€у垯鏇村鏉ユ簮浜庣儹寮曞彂鐨勫拰涓欑儻閰搁叝鐨勫姞鎴愬弽搴斻€傞櫎浜嗗墠闈㈡墍鎻愬強鐨凾MPMP(涓夌緹鐢插熀涓欑兎涓?3-宸熀涓欓吀閰?)銆丳ETMP(鍥?3-宸熀涓欓吀)瀛f垔鍥涢唶閰?绛夊瀹樿兘鐨勭~閱囦互澶栵紝鍙﹀涓€涓鍔犵~閱囨湰韬ǔ瀹氭€х殑鎬濊矾灏辨槸閲囩敤鑱氬悎鍨嬬殑纭唶锛屽(宸熀)涓欏熀鐢插熀纭呮哀鐑?MMSiO)鐨勮仛鍚堢墿锛屼互鍙婂叿鏈夋洿寮轰緵姘㈣兘鍔涘拰鏇村ソ绋冲畾鎬х殑鑺抽鏃忕~閱囥€侟/span>
銆€銆€鐮旂┒鍙戠幇锛屽浜庨噰鐢↖鍨嬪厜寮曞彂鍓傜殑鍙嶅簲锛屾坊鍔?.1%wt鐨?-宸熀鑻苟鍣佸攽(MBO)鍙互澧炲姞鍥哄寲閫熷害骞舵彁楂樻秱鑶滅殑鏈烘鎬ц兘锛屼絾鏇撮珮鐨勬坊鍔犻噺鍙嶈€屼細闄嶄綆鍙嶅簲閫熷害銆傝繖鏄洜涓虹敱浜庡弽搴旀棭鏈熶細娑堣€楁帀涔嬪墠鐨勬憾姘э紝浠庤€屽鍔犲弽搴旈€熷害锛屼絾鍚庢湡鐨勬阿杞Щ鍙嶅簲鍗翠細闃荤鐑峰熀鑷敱鍩虹殑閾惧闀垮弽搴斻€傚浜庨噰鐢↖I鍨嬪厜寮曞彂鍓傜殑鍙嶅簲锛屽弽搴旀槸閫熷害鍒欏拰澧炴劅鍓傘€佺矘搴︺€佸崟浣撲緵姘㈣兘鍔涗互鍙婃哀姘旂殑瀛樺湪涓庡惁鐩稿叧銆傚浜屽厓鍣诲攽鍖栧悎鐗〥BT鍙互澧炲姞姘╂皵鐜涓嬬殑鑱氬悎閫熷害锛屼絾鍦ㄦ哀姘旀儏鍐典笅鍒欐棤鏁堛€侟/span>
銆€銆€瀵逛簬纭唶鍖栧悎鐗╋紝浠庣~閱囧熀鍥㈣繛鎺ュ埌涓婚摼涓婇潰鐨勪綅缃紝鎴戜滑鍙互鍒嗕负涓€绾х~閱囧拰浜岀骇纭唶涓ょ被銆傚墠闈㈡彁鍒扮殑TMPMP鍜孭ETMP锛屼互鍙奣MPMA(涓夌緹鐢插熀涓欑兎涓?2-宸熀涔欓吀閰?)鍜孭ETMA(瀛f垔鍥涢唶鍥?宸熀涔欓吀)閰?锛岀敱浜庡矾鍩洪兘杩炴帴鍦ㄧ鍩虹殑浼綅涓婏紝閮藉睘浜庝竴绾х~閱囥€備竴绾х~閱囩殑娲绘€х浉瀵硅楂樹竴浜涳紝杩欎篃灏辨剰鍛崇潃鍏跺偍瀛樼ǔ瀹氭€х浉瀵规洿宸竴浜涖€傚彟澶栵紝涓€绾х~閱囩殑姘斿懗鐩稿涔熶細澶т竴浜涖€侟/span>