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1-Hydrosilatrane
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别名
283-60-3
1-Hydrosilatrane
Hydrosilatrane
Silatrane
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C6H13NO3Si |
| Molecular weight | 175.26 |
| Application【应用】 | 1-Hydrosilatrane is an air- and moisture-stable hydride reducing reagent that exhibits high functional group compatibility. The Adler group has used 1-hydrosilatrane for the reduction of ketones and aldehydes as well as the direct reductive amination of ketones under mild conditions. |
| Other Notes【其他说明】 | Chiral Bronsted Acid-Catalyzed Metal-Free Asymmetric Direct Reductive Amination Using 1-Hydrosilatrane Silatrane as a Practical and Selective Reagent for the Reduction of Aryl Aldehydes to Benzylic Alcohols |
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性质
| Assay【测定】 | ≥95% |
| form【形式】 | powder or crystals |
| reaction suitability | reagent type: reductant |
| mp | 249-256 ℃ |
| storage temp.【储存温度】 | −20℃ |
| InChI | 1S/C6H12NO3Si/c1-4-8-11-9-5-2-7(1)3-6-10-11/h1-6H2 |
| InChI key | XBRVPWBNRAPVCC-UHFFFAOYSA-N |
安全信息
| Storage Class Code【储存分类代码】 | 11 - Combustible Solids |
| WGK | WGK 3 |
