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中心 > 811794-35-1， [(Cp)Ru(η6-naphthalene)]OTf
[(Cp)Ru(η6-naphthalene)]OTf
| 半岛bd体育手机客户端 编号： | 4074634 |
| 规格： | ≥95% |
| CAS NO： | 811794-35-1 |
| 包装规格： | 250 MG，1 G |
| 半岛bd体育手机客户端 类别： | 进口试剂 |
| 品牌： | Sigma-Aldrich |
| 优惠价： | 立即咨询 |
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别名
811794-35-1
[(Cp)Ru(η6-naphthalene)]OTf
(η5-Cyclopentadienyl)(η6-naphthalene)ruthenium(1+) trifluoromethanesulfonate
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C16H13F3O3RuS |
| Molecular weight | 443.40 |
| Application【应用】 | Stable precursor for synthesis and ruthenium catalysis. It was also used by the Ritter lab to synthesize an Fmoc-protected ruthenium tyrosine for subsequent incorporation of the [18F]fluoride radiolabel into polypeptides. |
| Other Notes【其他说明】 | Site-Specific Deoxyfluorination of Small Peptides with [18F]Fluoride Comparison of the Catalytic Activity of [(5-C5H5)Ru(2,2′-bipyridine)(L)]OTf versus [(5-C5H5)Ru(6,6′-diamino-2,2′-bipyridine)(L)]OTf (L = labile ligand) in the Hydrogenation of Cyclohexanone. Evidence for the Presence of a Metal–Ligand Bifunctional Mechanism under Acidic Conditions Arene Exchange in the Ruthenium-Naphthalene Complex [CpRu(C10H8)]+ |
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性质
| Assay【测定】 | ≥95% |
| form【形式】 | powder |
| reaction suitability | reagent type: catalyst reaction type: C-C Bond Formation |
| mp | 112-116 ℃ |
| storage temp.【储存温度】 | 2-8℃ |
安全信息
| Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
