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CLAmP
半岛bd体育手机客户端 别名
CLAmP
Heller-Sarpong Reagent
N-Methoxy-N-methyl-1H-pyrrole-1-carboxamide
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 |
C
7H
10N
2O
2
|
| Molecular weight |
154.17
|
| PubChem Substance ID【PubChem化学物质编号】 |
329769111
|
| Application【应用】 |
The CLAmP (Carbonyl Linchpin
N,
O-dimethylhydroxylamine pyrrole) reagent, reported by Sarpong and Heller, is a useful building block for the efficient synthesis of unsymmetrical ketones. CLAmP shows high versatility based on compatibility with both highly reactive, thermally unstable nucleophiles as well as less reactive stable nucleophiles. It reacts with Grignard reagents to form the corresponding Weinreb amides.
|
| Other Notes【其他说明】 |
One-pot Unsymmetrical Ketone Synthesis Employing a Pyrrole-Bearing Formal Carbonyl Dication Linchpin Reagent
|
半岛bd体育手机客户端 性质
| form【形式】 |
liquid
|
| Quality Level【质量水平】 |
100
|
| refractive index【折射率】 |
n
|
| density |
1.126 g/mL
|
| storage temp.【储存温度】 |
2-8℃
|
| SMILES string |
O=C(N(OC)C)N1C=CC=C1
|
| InChI |
1S/C7H10N2O2/c1-8(11-2)7(10)9-5-3-4-6-9/h3-6H,1-2H3
|
| InChI key |
NLSJGNBOCVXWHS-UHFFFAOYSA-N
|
| packaging【包装】 |
1 g in glass bottle
|
安全信息
| Storage Class Code【储存分类代码】 |
10 - Combustible liquids
|
| WGK |
WGK 3
|
| Flash Point(F)【闪点(F)】 |
230.0 °F
|
| Flash Point(C)【闪点(C)】 |
110 ℃
|
