Technical Notes:
1. Catalyst used for tandem asymmetric cyclopropanation/Cope rearrangement.
2. Catalyst used for an asymmetric4 + 3cycloaddition.
References:
1. Angew. Chem. Int. Ed., 2009, 48, 2398.
2. Org. L ett., 2008, 10, 573.
Strem
氯(2 -二环己基膦基-2',6'-二-异丙氧基-1,1'-联苯基)(2 -氨基-1,1'-联苯-2 -基)钯(II), Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
甲烷磺酸基(2-(二叔丁基膦)-3-甲氧基-6-甲基,2',4',6'-三异丙基-1,1'-联苯基)(2'-氨基-1,1'-联苯基-2-基)钯(II), Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
甲烷磺酸(2-二环己基膦基-2',4',6'-三-异丙基-1,1'-联苯基)(2'-氨基-1,1'-联苯-2-基)钯(II), Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
氯{[Brettphos][2-(2-氨基乙基苯基]钯(II)]}/[Brettphos]混合物(PdP/P摩尔比为1:1), Chloro{[BrettPhos][2-(2-aminoethylphenyl]palladium(II)]}/[BrettPhos] admixture (molar PdP/P = 1:1)
甲磺酸盐[9,9-二甲基-4,5-双(二苯基膦基)呫吨](2'-甲基氨基-1,1'-联苯-2-基)钯(II), Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene](2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
双(二苯基膦苯基醚)二氯化钯(II), Dichloro{bis[2-(diphenylphosphino)phenyl]ether}palladium(II)
Dichloro(1,5-cyclooctadiene)palladium(II)
(1,5-环辛二烯)二氯化钯(II)
甲磺酰胺{N-[2-(二-1-金刚烷基膦基)苯基]吗啉}(2'-氨基-1,1'-联苯-2-基)钯(II)二氯甲烷加合物[Mor-Dalphos Palladacycle Gen. 3], Methanesulfonato{N-[2-(di-1-adamantylphosphino)phenyl]morpholine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct
钯碳-1wt%负载, Palladium on carbon - 1 wt % loading
5%钯碳, Palladium