Technical Notes:
1.Rhodium-catalyzed regio- and stereoselective addition of dip henylphosphine oxide to alkynes .
2. Rhodium- catalyzed hydrophosphinylation.
References:
1. Org. Lett., 2008. 10, 3141.
2. J. Org. Chem., 2001, 66, 5929.
Strem
Rhodium
(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
(R)-(+)-2,2',6,6'-四甲氧基-4,4'-二(二苯基膦基)-3,3'-联吡啶(1,5-环辛二烯)铑(I)四氟硼酸
1,2-双((2S,5S)-2,5-二乙基膦酸)乙烷(环辛二烯)铑(I)三氟甲磺酸盐, 1,2-Bis((2S,5S)-2,5-diethylphospholano)ethane(cyclooctadiene)rhodium(I) trifluoromethanesulfonate
1,1双((2S,5S)-2,5 - 二甲基膦)二茂铁(环辛二烯)铑(I)四氟硼酸盐, 1,1’-Bis((2S,5S)-2,5-dimethylphospholano)ferrocene(cyclooctadiene)rhodium(I) tetrafluoroborate
1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene(1,4-naphthoquinone)palladium(0) dimer
1,3-双(2,6-二-异丙苯基)咪唑-2-基1,4-萘醌)钯二聚物
Bis(tricyclohexylphosphine)palladium(0)
双(三环己基膦)钯
甲磺酸根(二金刚烷基-正丁基膦基)-2'-氨基-1,1'-联苯-2-基)钯(II)二氯甲烷加合物, Methanesulfonato(diadamantyl-n-butylphosphino)-2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct
氯(2-二环己基膦-3,6-二甲氧基-2',4',6'-三-异丙基-1,1'-联苯)(2'-氨基-1,1'-联苯-2-基)钯(II), Chloro(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
甲磺酸(2-二环己基膦基-2',6'-二异丙氧基-1,1'-联苯基)(2-氨基-1,1'-联苯-2-基)钯(II), Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
甲磺酸[2-二乙基膦-2',6-双(二甲氨基)-1,1-二苯基](2'-氨基-1,1'-联苯-2-基)钯(II), Methanesulfonato[2-diethylphosphino-2',6'-bis(dimethylamino)-1,1-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)