Technical Notes:
1. Ruthenium-catalyzed vinylic substitution reactions.
2. Ruthenium-catalyzed oxypropargylation of alkenes.
References:
1. J. Am. Chem. Soc., 2008, 130, 2908. 2. Organometallics, 2009, 28, 48.
Strem
二氯[(S)-(-)-2,2'-双(二苯基膦基)-1,1'-联萘[(S)-(-)-2-(α-(i-丙基)甲胺)-1H-苯并咪唑]钌(II), Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(S)-(-)-2-(α;-(i-propyl)methanamine)-1H-benzimidazole]ruthenium(II)
羰基[5,10,15,20-四(2,4,6-三甲基苯基)-21H,23H-卟啉]钌(II), Carbonyl[5,10,15,20-tetrakis(2,4,6-trimethylphenyl)-21H,23H-porphinato]ruthenium(II)
氯(对伞花烃)[(1R,2R)-(-)-2-氨基-1,2-二苯乙基(甲磺酰氨基)]钌(II), Chloro(p-cymene)[(1R,2R)-(-)-2-amino-1,2-diphenylethyl(methylsulfonylamido)]ruthenium(II) RuCl(p-cymene)[(R,R)-MsDpen]
Ruthenium
钌,0.5%在碳上
二氯[(R)-双(二苯基膦基)-1,1-联萘][1S,2S)-2-氨基-1-苯基丙基二苯基膦]钌(II), Dichloro[(R)-bis(diphenylphosphino)-1,1-binaphthyl][1S,2S)-2-amino-1-phenylpropyldiphenylphosphine]ruthenium(II)
氯[(S)-(-)-2,2'-双[二苯基膦基]-1,1'-联萘][(S)-1,1-双(4-甲氧基苯基)-3-甲基丁烷-1,2-二胺]钌(II)四氟硼酸盐, Chloro[(S)-(?)-2,2′-bis[diphenylphosphino]-1,1′-binaphthyl][(S)-1,1-bis(4-methoxyphenyl)-3-methylbutane-1,2-diamine]ruthenium(II) tetrafluoroborate
{[(1S,2S)-2-氨基-1,2-二苯基乙基](4-甲苯磺酰基)酰氨基}(对-伞花烃)钌(II)四氟硼酸盐, {[(1S,2S)-2-Amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) tetrafluoroborate
三环[1,3 -二(2,4,6三甲苯)咪唑- 2 -亚基] [2 -噻吩亚甲基]钌, Tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene][2-thienylmethylene]ruthenium(II) dichloride
双(1,1,1-三氟-2,4-戊二酮)(1,5-环辛二烯)钌(II), Bis(1,1,1-trifluoro-2,4-pentanedionato)(1,5-cyclooctadiene)ruthenium(II)
(-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
(-)-1,2-双((2R,5R)-2,5-二乙基膦)苯(环辛二烯)四氟硼酸铑