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位置: 首页> 品牌> Strem> 二甲基铵二氯三(μ-氯)双{(R)-(+)-5,5'-双[二(3,5-二甲苯基)膦基] -4,4'-双-1,3-苯并间二氧杂环戊烯}二钌(II)

Dimethylammonium dichlorotri(mu-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos?)}2(mu-Cl)3]

二甲基铵二氯三(μ-氯)双{(R)-(+)-5,5'-双[二(3,5-二甲苯基)膦基] -4,4'-双-1,3-苯并间二氧杂环戊烯}二钌(II)

品牌
Strem
CAS
935449-46-0
货号
44-0520
包装型号
规格纯度
价格
960 *本价格含增值税费
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半岛bd体育手机客户端 名称:
935449-46-0
Dimethylammonium dichlorotri(mu-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos?)}2(mu-Cl)3]
二甲基铵二氯三(μ-氯)双{(R)-(+)-5,5'-双[二(3,5-二甲苯基)膦基] -4,4'-双-1,3-苯并间二氧杂环戊烯}二钌(II)
半岛bd体育手机客户端 介绍:

Technical Notes:

1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-S EGPHOS? ligand, as the ruthenium complex, gives superior

enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of a-substituted-?-ketoesters. See 15-0066.

2.Ruthenium catalyzed enantioselective synthesis of ? amino acids by hydrogenation

3.Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone. See 44-0098 for Ru catalyst.

References:

1. U.S. Pat. 7626034.

2. U.S. Pat 7462722.

Strem

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