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位置: 首页> 品牌> Strem> 二甲基氨基二氯三(μ-氯)双[(R)-(+)-2,2'-双(二苯基膦基)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘]二钌(Ⅱ)

Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(mu-Cl)3]

二甲基氨基二氯三(μ-氯)双[(R)-(+)-2,2'-双(二苯基膦基)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘]二钌(Ⅱ)

品牌
Strem
CAS
2378771-65-2
货号
44-0516
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价格
1245 *本价格含增值税费
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半岛bd体育手机客户端 名称:
2378771-65-2
Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(mu-Cl)3]
二甲基氨基二氯三(μ-氯)双[(R)-(+)-2,2'-双(二苯基膦基)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘]二钌(Ⅱ)
半岛bd体育手机客户端 介绍:

Technical Notes :

1. Biaryl bisphosphine ligand. The Ha-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturate carboxylic acids to a higher ee than does BINAP. (Ref. 1,2)

2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug lbuprofen.

References:

1. J. Org. Chem.. 1996. 61. 5510

2. Topics Organometal. Chem. 2004, 6. 63 (review).

Strem

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