Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos?]

Diacetato{(R)-(+)-5,5'-双[二(3,5-二甲苯基)膦]-4,4'-双- 1,3 -苯并二氧杂环戊烯}钌(II)

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Strem

CAS

944450-49-1

货号

44-0174

包装型号

规格纯度

价格

960 元 *本价格含增值税费

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数量

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半岛bd体育手机客户端名称：

944450-49-1
Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos?]
Diacetato{(R)-(+)-5,5'-双[二(3,5-二甲苯基)膦]-4,4'-双- 1,3 -苯并二氧杂环戊烯}钌(II)

半岛bd体育手机客户端介绍：

Technical Notes:

1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS"? ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of a-sub stituted-?-ketoesters. See 15-0066.

2. Ruthenium catalyzed enantioselective synthesis of ? amino acids by hydrogenation.

References:

1. US. Pat. 7626034

Strem

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羰基氯醇[双(2-二叔丁基膦乙基)胺]钌(II), Carbonylchlorohydrido[bis(2-di-t-butylphosphinoethyl)amine]ruthenium(II)

Ruthenium(III) Acetylacetonate

乙酰丙酮钌(III)

Ruthenium(III) nitrosyl nitrate

三硝基亚硝酰钌

Ruthenium

二氯二[3-(二苯基膦基)]丙基胺]钌(II), Dichlorobis[3-(diphenylphosphino]propylamine]ruthenium(II)

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