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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap]

二乙酸根[(R)-(+)-2,2'-二(二苯基膦基)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘基]钌(II)

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Strem
CAS
374067-51-3
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44-0166
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374067-51-3
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap]
二乙酸根[(R)-(+)-2,2'-二(二苯基膦基)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘基]钌(II)
半岛bd体育手机客户端 介绍：

Technical Notes:

1.Biaryl bisphosphine ligand. The Ha-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP. (Ref. 1,2)

2.The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug lbuprofen.

References:

1. Org. Chem.. 1996, 61. 5510.

2. Topics Organometal. Chem. 2004, 6, 63 (review).

Strem

推荐半岛bd体育手机客户端

二氯[(S )-(+)- 4,12 -双(二(3,5 -二甲苯基)膦)-[2.2],对环芳烷] [(1R,2R)-(+)- 1,2 -二苯基]钌, Dichloro[(S)-(+)-4,12-bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)

Dichlorotricarbonylruthenium(II) dimer

二氯三羰基钌

二甲基铵二氯三(μ-氯)双{(R)-(+)-5,5'-双[二(3,5-二甲苯基)膦基] -4,4'-双-1,3-苯并间二氧杂环戊烯}二钌(II), Dimethylammonium dichlorotri(mu-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos?)}2(mu-Cl)3]

Hexaammineruthenium(III) chloride

三氯化六铵合钌

[1,3-双(2,4,6-三甲基苯基咪唑烷-2-亚基)(三环己基膦)-(2-氧代亚苄基)氯化钌(VI), [1,3-Bis(2,4,6-trimethylphenylimidazolidin-2-ylidene)](tricyclohexylphosphine)-(2-oxobenzylidene)ruthenium(II) chloride LatMet

1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)

1-羟基四苯基环戊二烯

二氯[(S)-(-)-2,2'-双(二-对-甲苯基膦基)-1,1'-联萘[(S)-(-)-2-(α-甲基甲酰胺基)-1H-苯并咪唑]钌(II), Dichloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl][(S)-(-)-2-(α;-methylmethanamine)-1H-benzimidazole]ruthenium(II)

六氰基钌酸四钾盐水合物, Potassium hexacyanoruthenate(II) hydrate

四氧化钌, Ruthenium(VIII) oxide

Ruthenium

钌,活性炭5%
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