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Chloro{(R)-(-)-1,13-bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin}(p-cymene)ruthenium(II) chloride (R)-C3-TUNEPHOS-Ru

(R)-C3-TUNEPHOS-钌络合物

品牌
Strem
货号
44-0109
包装型号
规格纯度
价格
1425 *本价格含增值税费
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半岛bd体育手机客户端 名称:
Chloro{(R)-(-)-1,13-bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin}(p-cymene)ruthenium(II) chloride (R)-C3-TUNEPHOS-Ru
(R)-C3-TUNEPHOS-钌络合物
半岛bd体育手机客户端 介绍:

Technical Notes:

1. New generation of chiral biaryl phosphine ligands with tunable dihedral angles. The ability to

modify the dihedral angle allows for the fine tuning of the catalyst system and optimization of enantioselectivity. See 15-0175.

2.Ru-C3-TUNEPHOS complexes are used for asymmetric hydrogenation of ?-ketoesters , enol acetates-, cyclic ?-amino acids, a-phthalimide ketones . and a-keto esters .

References:

1. J. Org.Chem., 2000, 65, 6223.

2.Org. Lett., 2002, 4, 4495.

3.J. Am. Chem. Soc., 2003, 125, 9570. .

4.J.Am. Chem. Soc., 2004, 126, 1626.

5.Synlett., 2006, 126, 1169.

Strem

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