Technical Notes:

1.Catalytic enantioselective synthesis of vicinal dialkyI arrays.

2.Catalytic asymmetric conjugate addition of Grignard reagents to chromones.

3.Rh-Catalyzed highly enantioselective hydroalkynylation reaction of norbornadiene derivatives

4.Copper-Catalyzed enantioselective alkylation of enolizable ketimines with organomagnesium reagents .

5.Enantioselective synthesis of boryl tetrahydroquinolines via Cu-Catalyzed hydroboration.

6.Copper-Catalyzed regio- and enantioselective addition of silicon Grignard Reagents to alkenes activated by azaaryl groups

7.Ligand for Cu-catalyzed Asymmetric Conjugate Reduction of ?-Boronyl-?-alkyI enoates .

8.Ligand for Cu-catalyzed Asymmetric Alkylation of Acylsilanes .

9.Ligand for Cu-catalyzed Asymmetric Addition of Grignard Reagents to Alkenyl-substituted Aromatic N-Heterocycles