Technical Notes:

1.Ligand for Palladium-catalyzed amination of aryl halides .

2.Ligand for Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene .

3.L igand for Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with orga noboronic acids .

4. L igand for Copper catalyzed asymmetric 1 ,4 -hyd rosilylations of a,?-unsaturated esters .

5. L igand for Ruthenium-catalyzed asymmetric hyd rogenation of N-sulfonated-a-dehydroamino acids .

6.L igand for Rhodium-catalyzed a symmetric hydrogenation of enamines

7.Ligand for Palladium-catalyzed Kumada coupling of aryl and vinyl tosylates.

8.L igand for Palladium-catalyzed enantioselective synthesis of aryl sulfoxides .

9. L igand for Rhodium-catalyzed enantioselective insertion of a carbenoid carbon into a c-c bond.

10.L igand for Rh-catalyzed Asymmetric Hydrogenation of enamine substrates.