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(11aS)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1’,7’-ef]phosphocin

(11aS)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1’,7’-ef]phosphocin

品牌
Strem
CAS
885701-78-0
货号
15-5185
规格纯度
min. 97%
价格
1335 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
- +
半岛bd体育手机客户端 名称:
885701-78-0
(11aS)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1’,7’-ef]phosphocin
(S)-SITCP
半岛bd体育手机客户端 介绍:

Technical Note:

1. Phosphine -catalyzed intra-and intermolecular gamma-addition of nitrogen nucleophiles to allenoates and alkynoates.

2.Catalytic asymmetric construction of the tryptanthrin skeleton via enantioselective decarboxylativo4+2cyclization.

3.Catalytic, enantioselective carbon-oxygen bond formation - phosphine-catalyzed synthesis of benzylic esters via oxidation of benzylic C-H bonds.

4.Use of a new spirophosphine to achieve catalytic, enantios elective4+ 1annulations of amines with allenes to generatedihydropyrroles.

References: 1.Angew. Chem. Int. Ed.2013, 52, 2525. 2.Org. Lett.. 2017, 19, 3219 3.J. Am. Chem. Soc.. 2016, 138, 12069. 4.J. Am. Chem. Soc.. 2015, 137, 3803

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