Technical Note:
1.Catalyst for the enantioselective cyanosilylation of aromatic ketones using chiral lithium salts of (R)-BINOL- or (S)- BINAM-derived phosphoric acid compounds .
Reference:
1. Angew. Chem. Int. Ed., 2009, 48, 7428-7431.
Strem
(11bR)-8,9,10,11,12,13,14,15-八氢-4-羟基-2,6-二甲基-2-萘基-4-氧化物二萘并[2,1-d:1',2'-f][1,3,2]二噁磷杂庚英, (11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(11BS)-4-羟基-2,6-二-1-萘基-4-氧化物二萘并[2,1-d:1',2'-f][1,3,2]二噁磷杂庚英, (11bS)-4-Hydroxy-2,6-di-1-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
Di-2-norbornylphosphine
二-2-降冰片基膦(内型和外型异构体的混合物)
(3aS,8aS)-(+)-4,4,8,8四(3,5-二甲基苯基)四氢-2,2-二甲基-6-苯基-1,3-二氧杂环戊烯并[4,5-E]二噁磷杂庚英, (3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin
(S)-(-)-7-[N-(1,3-二噻烷-2-基)甲基氨基]-7'-[二(3,5-二叔丁基苯基)膦基]-2,2',3,3'-四氢-1,1'-螺二茚, (S)-(-)-7-[N-(1,3-Dithian-2-yl)methylamino]-7'-[bis(3,5-di-t-butylphenyl)phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobindane
(R)-2,2'-双[二(3,5 -二甲基苯基)膦基] -4,4',6,6'-四甲氧基联苯, (R)-2,2'-Bis[bis(3,5-dimethylphenyl)phosphino]-4,4',6,6'-tetramethoxy-)-1,1'-biphenyl
1-Diphenylphosphino-2-(N,N-dimethylamino)-1H-indene
1-二苯基膦基-2-(N,N-二甲基氨基)-1H-茚
(S)-(-)-4-[2-(二苯基膦)- 1 -萘]- N-[(R)- 1-苯乙基] -1-二氮杂萘胺, (S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine
二苯基[3-(三乙氧基甲硅烷基)丙基]膦, Diphenyl[3-(triethoxysilyl)propyl]phosphine
R)-4-(蒽-9-基)-3-(叔丁基-2,3-二氢苯并[d] [1,3]氧杂磷杂环孔, (R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole