(S)-(+)-4,12-二(二(3,5-二甲苯基)膦)-[2.2]-对环芳烷

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(S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane
(S)-(+)-4,12-二(二(3,5-二甲苯基)膦)-[2.2]-对环芳烷

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Technical Notes:

1.See 15-0426

2.Chiral ligand employed in the enantioselective hydrogenation of various ketones.

3.Chiral ligand employed in the enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes.

4.Chiral ligand employed in the enantioselective 2 +2 cycloaddition of oxa bicyclic alkenes with terminal alkynes.

5.Chiral ligand employed in the gold-catalyzed enantioselective Cope rearrangement of achiral 1,5-dienes.

References: 1.Org. L ett., 2000, 2, 4173. 2.Angew. Chem. Int. Ed., 2010, 49, 9197. 3.Org. L ett., 2010, 12, 304. 4Nature Chemistry, 2012, 4, 405.

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