Technical Notes:
1.Commonly employed chiral ligand for L ewic acid catalyzed transformations, including
cyclopropanation, carbonyl-ene, Michael, aldol, Henry, Diels-Alder and hetero Diels-Alderreactions.
2.Utilized in Methoxylcarbonylation of terminal alkynes.
3.L igand used in the asymmetric Kumada-cross coupling of secondary alkyI halides
4.L igand used for 5-endo-dig Carbocylization
5.L igand use for reductive acyl cross-coupling