AEM
anion exchange membrane锛岄槾绂诲瓙浜ゆ崲鑶溿€侽H-鍙互绉诲姩鐨勩€侟/span>
AFC
alkaline fuel cell锛岀⒈鎬х噧鏂欑數姹犮€備娇鐢ㄧ⒈鎬х數瑙ｆ恫銆傝浇浣撶殑绂诲瓙鏄阿姘ф牴绂诲瓙(OH-)銆侟/span>
AMFC
anion exchange membrane fuel cell锛屼娇鐢ㄩ槾绂诲瓙浜ゆ崲鑶滅殑纰辨€х噧鏂欑數姹犮€侟/span>
CHP
combined heat and power锛岀儹鐢佃仈浜с€傛湁鏁堝埄鐢ㄤ笌鍙戠數鐩稿叧鐨勭儹鑳斤紝鎻愰珮鑳芥簮鏁堢巼鐨勭郴缁熴€傚簲鐢ㄤ簬楂樻俯鐕冩枡鐢垫睜(SOFC銆丮CFC鍜孭AFC)銆侟/span>
CO鑰愬彈鎬?/span>
閾傜數鏋佸緢瀹规槗琚竴姘у寲纰充腑姣掞紝绉颁负浣嶤O鑰愬彈鎬с€備腑姣掓椂锛屽偓鍖栨椿鎬ч檷浣庛€侟br/>
鍌寲鍓備腑姣扅/span>
鐕冩枡涓殑鏉傝川(涓€姘у寲纰矯O鍜岀～榛?涓庡偓鍖栧墏鐨勬椿鎬т綅缁撳悎锛屼粠鑰屼娇寰楀偓鍖栧墏澶卞幓娲绘€с€侟/span>
DEFC
direct ethanol fuel cell锛屼竴绉嶇洿鎺ュ皢鐕冩枡涔欓唶鐢ㄤ簬闃虫瀬姘у寲鍙嶅簲鐨勭噧鏂欑數姹犮€備娇鐢ㄤ笌PEMFC鐩稿悓鐨勭數瑙ｈ川鑶溿€侟/span>
鐢垫笚閫忔祦閲廃/span>
鍦ㄥ浐浣撶瀛愪氦鎹㈣啘绫诲瀷(濡侾EMFCs銆丏MFCs)涓紝闅忕潃璐ㄥ瓙鐨勭Щ鍔紝姘村悎姘村彂鐢熺殑绉诲姩銆侟/span>
鍙犲眰
鍙犲姞寮忕粨鏋勶紝鍗曚綋鐢垫睜鐩镐簰鍙犲姞锛屼互杈惧埌鎵€闇€鐨勭數鍔ㄥ姏銆侟/span>
DMFC
direct methanol fuel cell锛岀洿鎺ュ埄鐢ㄧ噧鏂欑敳閱囪繘琛岄槼鏋佹哀鍖栧弽搴旂殑鐕冩枡鐢垫睜锛岀數鑽风殑杞戒綋绂诲瓙鏄川瀛愩€備娇鐢ㄤ笌PEMFC鐩稿悓鐨勭數瑙ｈ川鑶溿€侟/span>
澶氬瓟鐢垫瀬
澧炲姞琛ㄩ潰绉鎻愰珮鐢垫瀬姘у寲鍜岃繕鍘熷弽搴旂殑鏁堢巼闈炲父閲嶈銆備负姝ょ數鏋佽鍒舵垚澶氬瓟缁撴瀯銆備篃绉颁负澶氬瓟鐢垫瀬銆備娇鐢ㄧ⒊甯冨拰纰崇氦缁寸瓑浣滀负鐢垫瀬楠ㄦ灦銆侟/span>
EOR
ethanol oxidation reaction锛岀洿鎺ヤ箼閱囩噧鏂欑數姹犻槼鏋佺殑涔欓唶姘у寲鍙嶅簲銆侟/span>
GDE
gas diffusion electrode锛屾皵浣撴墿鏁ｇ數鏋併€侟/span>
杩囩數鍘婞/span>
鐢变簬骞宠 鐢典綅涓嬬數鑽疯浆绉诲お鎱㈣€屽繀椤绘柦鍔犵殑棰濆鐢典綅宸О涓烘椿鍖栬繃鐢靛帇(鏋佸寲)銆傚叾浠栫被鍨嬬殑杩囩數鍘嬪寘鎷敱鏈夋簮鍏冧欢鏃犳硶璺熶笂浼犺緭閫熺巼鑰屽紩璧风殑杩囩數鍘嬪拰鐢辨濮嗙數闃诲紩璧风殑杩囩數鍘嬨€傚湪鐕冩枡鐢垫睜涓紝闃存瀬鐨勬哀杩樺師鍙嶅簲寮曡捣鐨勬瀬鍖栦竴鑸緝澶э紝鐩墠姝ｅ湪缁х画鐮旂┒浠ヨ幏寰楀彲闄嶄綆鏋佸寲鐨勯珮娲绘€у偓鍖栧墏銆侟/span>
鍥轰綋姘у寲鐗╃噧鏂欑數姹?SOFC)
鍦ㄩ珮娓╀笅浣跨敤銆備娇鐢ㄦ哀绂诲瓙浼犲鎬у浐浣撶數瑙ｈ川(YSZ)銆俌SZ涓哄浐浣擄紝娌℃湁娉勬紡鐨勯闄╋紝鍥犺€岃璁や负MCFC绋冲畾銆侟br/>姣忎釜鐢垫瀬鐨勫弽搴旀槸
闃虫瀬鍙嶅簲 H2+ O2-鈫扝2O + 2e
闃存瀬鍙嶅簲锛?.5O2+ 2e鈫 O2-
鍥轰綋绂诲瓙浜ゆ崲鑶滃紡鐕冩枡鐢垫睜
璐ㄥ瓙浜ゆ崲鑶滅被鍨嬶細PEMFC
楂樺垎瀛愮數瑙ｈ川绫诲瀷锛歅EFC
鐢查唶鐕冩枡鐢垫睜锛欴MFC
鐢佃В璐ㄦ槸鍦ㄤ晶閾惧叿鏈夌：閰稿熀鐨勭壒姘熼緳鍩哄浐浣撶瀛愪氦鎹㈤珮鍒嗗瓙鑶?涓嶱EMFC鍑犱箮鐩稿悓)銆傛惡甯︾數鑽风殑绂诲瓙鏄川瀛?H+)銆傜敱浜庡叾鍏锋湁涓綆娓╂搷浣滐紝浣庢俯鍚姩鍜岄珮鑳介噺瀹归噺绛夌壒鎬э紝姝ｅ湪琚爺绌朵綔涓烘苯杞︾殑鍔ㄥ姏婧愩€侟br/>闃存瀬鍙嶅簲 0.5O2+ 2H++ 2e 鈫 H2O
闃虫瀬鍙嶅簲 H2鈫?H++ 2e
鐒惰€岋紝浣滀负鐕冩枡鐨勬阿鐨勫瓨鍌紝琛ュ厖浠ュ強鍩虹璁炬柦寮€鍙戠瓑渚濈劧闈复宸ㄥぇ鐨勬寫鎴樸€侟/span>
ICE
internal combustion engine锛岄€氳繃鐕冪儳鐕冩枡浜х敓鏃嬭浆鑳介噺鑰屼骇鐢熷姩鍔涚殑鏈哄櫒銆傚湪璁ㄨ鐕冩枡鐢垫睜鐨勬椂鍊欙紝缁忓父琚敤鏉ヤ笌鐕冩枡鐢垫睜鐩稿鐓с€侟/span>
鐢查唶鐕冩枡鐢垫睜(DMFC)
褰撲娇鐢ㄤ笌PEMFC(閰告€х數瑙ｈ川)涓娇鐢ㄧ殑绂诲瓙浜ゆ崲鑶滅殑鐩稿悓绫诲瀷鐨勭瀛愪氦鎹㈣啘鏃讹紝闃存瀬鐨勭數鏋佸弽搴斾负锛?.5O2+ 6H++ 6e 鈫 3H2O锛涘湪闃虫瀬鐨勭數鏋佸弽搴斾负锛欳H3OH + H2O 鈫 CO2+ 6H++ 6e锛涙€诲弽搴斾负锛欳H3OH + 1.5O2鈫扖O2+ 2H2O锛涚己鐐规槸鐢查唶浜ゅ弶鍜屽弽搴旈€熷害鎱€€侟br/>鍦ㄧ⒈鎬х數瑙ｈ川涓嬶紝鐢垫瀬鐨勫弽搴旈€熷害蹇紝浣嗕簩姘у寲纰虫皵浣撶殑瀛樺湪鍜屾憾瑙ｅ害浣庣殑纰抽吀鐩愮殑褰㈡垚鏄富瑕佺己鐐广€侟br/>瀵逛簬浣跨敤闃寸瀛愪氦鎹㈣啘纰辨€х數瑙ｈ川鐨勯槾鏋佸弽搴斾负锛?.5O2+ 3H2O + 6e 鈫?OH-锛涢槼鏋佸弽搴旓細CH3OH + 6OH-鈫 CO2+ 5H2O + 6e锛汓br/>鎬诲弽搴斾负锛欳H3OH + 1.5O2鈫 CO2+ 2H2O銆侟/span>
纰辨€х噧鏂欑數姹?AFC)
浣跨敤纰辨€х數瑙ｆ恫銆傝浇浣撶殑绂诲瓙鏄阿姘ф牴绂诲瓙(OH-)銆傜敱浜庢哀杩樺師鍙嶅簲鍦ㄧ⒈鎬ф潯浠朵笅鏄揩閫熺殑锛屽洜姝ゅ彲浠ヤ娇鐢ㄩ櫎Pt鐢垫瀬浠ュ鐨勫叾浠栫數鏋侊紝浣嗘槸鍙︿竴鏂归潰锛岀己鐐规槸浜屾哀鍖栫⒊姘斾綋鐨勫瓨鍦ㄦ槸鏈夊鐨勩€?960骞翠唬鍒濇湡锛屽畠鍦ˋpollo椤圭洰涓娇鐢紝骞惰瘉鏄庢槸鏈夋晥鐨勶紝浣嗗悗鏉ュ湪Gemini椤圭洰涓敼涓篜EMFC銆侟br/>鐢佃В璐ㄦ槸KOH鎴朜aOH锛屾惡甯︾數鑽风殑绂诲瓙鏄疧H-銆傜敱浜庝簩姘у寲纰虫皵浣撶殑瀛樺湪锛屼骇鐢熺殑纰抽吀鐩愭憾瑙ｅ害寰堜綆锛岄€犳垚闂銆侟br/>鐢垫瀬鍙嶅簲濡備笅銆侟br/>闃存瀬鍙嶅簲 0.5O2+ H2O + 2e 鈫 2OH-
闃虫瀬鍙嶅簲 H2+ 2OH-鈫 2H2O + 2e
鎬诲弽搴旓細 H2+ 0.5O2鈫 H2O
瀹冧笌PEMFC鐨勪笉鍚屼箣澶勫湪浜庯紝鍦ㄩ槼鏋佷晶浼氱敓鎴愭按(鍦≒EMFC涓紝鍦ㄩ槾鏋佷晶浼氱敓鎴愭按)銆 OH-浠庨槾鏋佺Щ鍔ㄥ埌闃虫瀬锛屾按浠庨槼鏋佺Щ鍔ㄥ埌闃存瀬銆傚湪纰辨€ф潯浠朵笅锛岀數鏋佹椿鎬у緢楂橈紝浣嗕富瑕佺己鐐规槸绯荤粺鏈韩鐨勮€愪簩姘у寲纰虫€ц緝浣庛€侟/span>
鏋佸寲
鐢变簬鐢佃嵎杞Щ鍙嶅簲澶參鑰屽繀椤绘柦鍔犵殑鐢典綅宸О涓烘椿鍖栨瀬鍖栥€傚畠涔熻绉颁负婵€娲昏繃鐢靛帇銆傛澶栵紝杩樻湁涓庢墿鏁ｄ紶杈撴湁鍏崇殑浼犺緭鏋佸寲鍜岀敱娆у鐢甸樆寮曡捣鐨勭數闃绘瀬鍖栥€侟/span>
鏋佸寲鏇茬嚎
缁樺埗鐢垫睜鐢靛帇鍜岀數娴佸€肩殑鏇茬嚎銆傚畠鏄剧ず鐢变簬婵€娲绘瀬鍖栵紝浼犺緭鏋佸寲锛岀數闃绘瀬鍖栫瓑瀵艰嚧鐨勭數鍘嬮檷銆傝瘎浼扮噧鏂欑數姹犵壒鎬у拰鎬ц兘鎵€闇€鐨勯瑕佹祴閲忛」鐩€侟/span>
瀵勭敓鐢垫祦(parasitic current)
鐢变簬鍫嗘爤缁撴瀯锛屼笉鍚屽崟浣撳崟鍏冧箣闂存祦鍔ㄧ殑瀵硅緭鍑烘病鏈夎础鐚殑鐢垫祦銆侟/span>
LFFC
laminar flow fuel cell锛屽井娴佷綋鐕冩枡鐢垫睜銆備綔涓哄皬鍨嬮┍鍔ㄥ櫒鐢垫簮鐨勫紑鍙戞渶杩戝彉寰楁椿璺冦€侟/span>
绂昏仛浣掽/span>
鍦≒EMFC涓綔涓虹數瑙ｈ川娣诲姞鐨勫彲婧舵€у鐢甸珮鍒嗗瓙锛屽彲淇冭繘闃存瀬鍜岄槼鏋佸鐨勭數鏋佸弽搴斻€侟/span>
纾烽吀鐕冩枡鐢垫睜(PAFC)
浣滀负鍒嗘暎渚挎惡寮忓拰鍥哄畾寮忕噧鏂欑數姹犱娇鐢ㄦ渶涓哄箍娉涖€傛俯搴﹂€備腑(150-200鈩?銆傜數鑽疯浇浣?H+)鍜岀數鏋佸弽搴斾笌鍥烘€佺瀛愪氦鎹㈣啘鐕冩枡鐢垫睜鐩稿悓銆侟/span>
绂诲瓙浜ゆ崲鑶淈/span>
PEMFC涓娇鐢ㄧ殑鑶滄槸璐ㄥ瓙浜ゆ崲闃崇瀛?闃崇瀛?浜ゆ崲鑶溿€傜敱浜庡畠鐢卞熀浜庤仛鍥涙盁涔欑儻(浠ヨ仛姘熶箼鐑负楠ㄦ灦)骞跺湪渚ч摼鍏锋湁纾洪吀鍩虹殑楂樺垎瀛愯杽鑶滅粍鎴愶紝姘㈢瀛?璐ㄥ瓙)鍙互甯︾數鑽枫€傝繎鏉ワ紝鐢ㄤ簬纰辨€х數姹犵殑纰辨€т笅绋冲畾鐨勯槾绂诲瓙浜ゆ崲鑶滅殑寮€鍙戝彉寰楁椿璺冦€侟/span>
LSM
lanthanum strontium manganite锛岄敹鎺烘潅鐨勯敯閰搁暓(LaMnO3)銆傚畠琚敤浣淪OFCs姝ｆ瀬鐨勬哀杩樺師鐢垫瀬銆傚畠鏄竴绉嶇數瀛愬浣掽/span>
MCFC
molten carbonate fuel cell锛岀啍铻嶇⒊閰哥洂鐕冩枡鐢垫睜銆傝浇浣撶瀛愮⒊閰告牴绂诲瓙(CO32-)銆侟/span>
MEA
membrane electrode assembly锛岃啘鐢垫瀬澶嶅悎浣撱€侾EMFC绛夛紝鍏朵腑鍥轰綋浜ゆ崲鑶滃拰涓庡叾缁撳悎鐨勫偓鍖栧墏鐢垫瀬涓€浣撳寲銆侟/span>
MOR
methanol oxidation reaction锛屽湪鐢查唶鐕冩枡鐢垫睜鐨勯槼鏋佷笂鐩存帴杩涜鐢查唶姘у寲鍙嶅簲銆侟/span>
Nafion鑶淈/span>
涓€绉嶅叿鏈夌：閰稿熀銆佽川瀛愪氦鎹㈣兘鍔涘拰瀵肩數鎬х殑鍥涙盁涔欑儻鍩洪珮鍒嗗瓙銆侟/span>
鑳介噺瀹归噺
琛ㄧず鍙互浠庡崟浣嶉噸閲忔垨鍗曚綅浣撶Н鐨勭噧鏂欒幏寰楃殑鑳介噺銆備緥濡傦紝J/g锛學h/g锛學h/l锛宬Wh/g锛宬Wh/l绛?J涓篔ules锛學涓篧atts)銆俉鏄伐浣滐紝h鏄椂闂达紝涔樼Н鏄兘閲忋€備篃绉颁负鑳介噺瀵嗗害銆侟/span>
ORR
Oxygene Reduction Reaction锛屽湪姝ｆ瀬(闃存瀬)鍙戠敓鐨勬哀杩樺師鍙嶅簲銆侟/span>
PAFC
phosphoric acid fuel cell锛岀７閰稿瀷鐕冩枡鐢垫睜銆傝浇浣撶瀛愭槸璐ㄥ瓙銆侟/span>
PEFC
polymer electrolyte fuel cell锛岄珮鍒嗗瓙鐢佃В璐ㄧ噧鏂欑數姹犮€侟/span>
PEMFC
proton exchange membrane fuel cell鎴 polymer electrolyte membrane fuel cell锛岃川瀛愪氦鎹㈤珮鍒嗗瓙钖勮啘鍨嬬噧鏂欑數姹犮€侟/span>
姘㈡皵瀛樺偍
姘綔涓虹噧鏂欑殑瀛樺偍鏂规硶鍜屼緵搴旀柟娉?鍖呮嫭鍩虹璁炬柦)鏄噧鏂欑數姹犲疄闄呬娇鐢ㄤ腑鐨勪富瑕侀棶棰樸€傛湁楂樺帇缃?鐐稿脊)锛屼綆娓╂恫鍖栵紝鍏朵粬鍖栧悎鐗╃殑瀛樺偍锛屽寲鍚堢墿绛夛紝骞朵笖鐩墠姝ｅ湪涓嶆柇鎶ラ亾鍚庤€咃紝骞朵笌浜嬪疄娣蜂负涓€璋堛€侟/span>
姘㈡皵鏋?/span>
鐕冩枡鐢垫睜鐨勫彂鐢熸阿鐨勬哀鍖栧弽搴旂殑鐢垫瀬銆傚叾涓虹噧鏂欑數姹犵殑闃虫瀬銆侟/span>
姘斾綋鎵╂暎鐢垫瀬(GDE)
鍦≒EMFC鐨勬儏鍐典笅锛屽瀛旂數鏋佺敱鏀拺鍦ㄧ⒊棰楃矑涓婄殑瓒呯粏鍌寲鍓傞绮?鍏朵腑閾傛槸涓€涓吀鍨嬬殑渚嬪瓙)缁勬垚銆傝缁撴瀯琚涓虹敱浜叉按鐢佃В璐ㄩ儴鍒嗚鐩栫殑鍖哄煙鍜屽彲浠ヤ綔涓烘皵浣?鐕冩枡鍜屾哀鍖栧墏姘斾綋)鐨勯€氶亾鐢辩枏姘村尯鍩熷寘鍥寸殑寰┖闂寸粍鎴愩€傚畠鏈変竴涓噧鏂欏拰姘у寲鍓傛皵浣撶殑姘旂浉锛屽偓鍖栧墏锛岀數鏋佺浉浜掓帴瑙︾殑鐣岄潰銆傜⒊璐熻矗鐢靛瓙浼犲锛岀數瑙ｈ川璐熻矗绂诲瓙浼犲銆侟/span>
鐕冩枡閲嶆暣
閫氳繃鍌寲鍓傦紝鍖栧鍙嶅簲绛夊皢鐭虫补锛岀叅鐐紝澶╃劧姘旓紝娌兼皵绛夌敓鎴愭阿姘旂殑鍒舵阿鏂规硶銆侟/span>
鐕冩枡鐢垫睜(FC)
灏嗙噧鏂欑殑鍖栧鑳?鐗╄川鐨勫唴鑳?杞崲鎴愮數鑳界殑鍖栧瑁呯疆鍙堢О鐢靛寲瀛﹀彂鐢靛櫒銆傜數姹犵敱鍦ㄩ槼鏋?璐熸瀬)渚у彂鐢熺殑鐕冩枡(涓昏涓烘阿鍒嗗瓙;鍏朵粬鐢查唶锛屼箼閱囷紝鐢查吀绛?鐨勬哀鍖栧弽搴斾笌鍦ㄩ槾鏋?姝ｆ瀬)渚у彂鐢熺殑姘у寲鍓?涓昏涓烘哀鍒嗗瓙)鐨勮繕鍘熷弽搴旂粨鍚堣€屾垚銆傚叾鐗瑰緛鍦ㄤ簬锛屼笌鐑兘鍙戠數鐩告瘮锛屽叿鏈夋彁楂樿兘閲忓埄鐢ㄦ晥鐜囩殑鍙兘鎬с€侟/span>
鐔旇瀺纰抽吀鐩愮噧鏂欑數姹?MCFC)
鍦ㄩ珮娓?600-700鈩?涓嬩娇鐢ㄣ€傜數瑙ｆ恫(LiKCO3)鏄珮娓╂恫浣撱€侟br/>鍚勪釜鐢垫瀬鐨勫弽搴斿涓婞br/>闃虫瀬鍙嶅簲锛欻2+CO32-鈫扝2O + CO2+ 2e
闃存瀬鍙嶅簲锛?.5O2+ CO2+ 2e鈫扖O32-
鎬诲弽搴斿拰鍏朵粬FC涓€鏍锋槸锛欻2+ 0.5O2鈫扝2O
杞戒綋鐢佃嵎鏄瀛愮⒊閰告牴绂诲瓙(CO32-)銆傞槼鏋佺數鏋佹槸澶氬瓟閲戝睘闀嶏紝闃存瀬鏄瀛旀哀鍖栭晬(NiO)銆侟/span>
SAFC
solid alkaline fuel cell锛屼娇鐢ㄩ珮鍒嗗瓙鐢佃В璐ㄨ啘(闃寸瀛愪氦鎹㈣啘)鐨勭⒈鎬х噧鏂欑數姹犮€傝繎鏉ワ紝涓轰簡鍑忓皯浜屾哀鍖栫⒊姘斾綋鐨勫奖鍝嶏紝浜轰滑绉瀬寮€灞曚簡纰辨€х噧鏂欑數姹犵殑鐮旂┒銆侟/span>
娓楅€廃/span>
鍦―MFC涓紝鐕冩枡鐢查唶浠庨槼鏋佺數鏋佷晶娓楅€忓埌鍥轰綋鐢佃В璐ㄨ啘涓婏紝杩涘叆姘ф皵(闃存瀬)渚с€備竴鑸潵璇达紝鏄噧鏂欏悜闃存瀬渚ф笚閫忥紝瀵艰嚧鐢垫睜鐨勭數鍔ㄥ娍闄嶄綆銆侟/span>
姘寸鐞咟/span>
鍦ㄥ浐浣撻珮鍒嗗瓙鐢佃В璐ㄨ啘FCs(PEMFCs銆丄MFCs鍜孌MFCs)涓紝鍦ㄩ槾鏋佹垨闃虫瀬渚т細鏈夋按鐢熸垚銆傚洜姝ゅ彲鑳藉嚭鐜板惈姘撮噺杩囬珮鐨勬儏鍐点€傛澶栵紝鑶滅殑鐢靛鐜囧緢澶х▼搴︿笂鍙栧喅浜庡惈姘撮噺銆傛墍浠ヨ閫傚綋鎺у埗鍚按閲忋€侟/span>
姘存蹈
鍦ㄩ槾鏋佷骇鐢熸按鐨勬儏鍐典笅锛屽鍦≒EMFC涓紝姘存孩鍑哄埌闃荤姘斾綋鎵╂暎閫斿緞鐨勬儏鍐典笅锛屼細鍑虹幇娉涙互鐨勬儏鍐点€傛墍浠ユ按鍒嗙鐞嗛潪甯搁噸瑕併€侟/span>
SOFC
solid oxide fuel cell锛屼娇鐢ㄥ浐浣撴哀鍖栫墿(姘у寲閿嗘垨浜屾哀鍖栭搱锛涢攩鎴栭搱鐨勬哀鍖栫墿)浣滀负鐢佃В璐ㄧ殑鐕冩枡鐢垫睜銆傛渶楂樻俯搴?750鈩冭嚦1000鈩?瑙勬牸銆侟/span>
TPB
three phase boundary锛屼笁鐩哥晫闈紝鍌寲鍓傦紝姘旂浉锛岀數鏋佹帴瑙︾殑鐣岄潰銆傚湪SOFC鐨勬儏鍐典笅锛屾槸鎸嘚i鏋侊紝YSZ鍜屾皵鐩哥殑涓夌浉鐩告帴瑙︾殑鐣岄潰锛屾槸鐕冩枡姘у寲楂樻晥鍦拌繘琛岀殑鍦版柟銆侟/span>
鍥㈣仛浣掽/span>
鍒嗘暎鍦≒EMFC涓殑纰崇粏棰楃矑鐨勮仛闆嗕綋(绾崇背灏哄鐨勯搨缁嗛绮掍綔涓哄偓鍖栧墏璐熻浇鍦ㄨ〃闈笂)銆傚叾琛ㄩ潰瑕嗙洊鏈夌數瑙ｈ川婧舵恫锛屽苟涓斿瓨鍦ㄧ枏姘撮儴鍒嗭紝鍏朵腑鍙嶅簲姘斾綋閫氶亾閮ㄥ垎浜ょ粐鍦ㄨ糠璺腑銆侟/span>
寰祦浣撶噧鏂欑數姹燑/span>
灏忓瀷渚挎惡寮忕噧鏂欑數姹狅紝閲囩敤涓や釜寰昂搴﹀眰娴?闃虫瀬鍜岄槾鏋佷晶)銆傝櫧鐒剁敱浜庢墿鏁ｄ綔鐢紝鍦ㄥ瀭鐩翠簬灞傛祦鐨勬柟鍚戜笂鏈夋贩鏉傦紝浣嗗彧瑕佹贩鏉傛晥搴斾笉鍒拌揪鐢垫瀬锛屽氨涓嶉渶瑕佷氦鎹㈣啘绛夈€傝繖绉嶆柟娉曠殑浼樼偣鏄彲浠ユ牴鎹敤閫旇嚜鐢遍€夋嫨娑蹭綋鐨勬€ц川(pH鍊笺€佺噧鏂欍€佹哀鍖栧墏绛?銆侟/span>
姘ц繕鍘熷弽搴?ORR)
鍦ㄩ槾鏋佷笂鍙戠敓姘у垎瀛愮殑杩樺師鍙嶅簲銆傜敱浜?鐢靛瓙杩樺師鍙嶅簲浼撮殢鐫€姘?姘ч敭鐨勬柇瑁傦紝鍥犳鍙嶅簲閫熷害鎱紝浜х敓浜嗚緝楂樼殑杩囩數鍘嬶紝杩欐槸鐢垫睜鐢靛姩鍔块檷浣庣殑涓昏鍘熷洜銆傛澶栵紝杩囨哀鍖栨阿鐨勫舰鎴愯繃绋嬮儴鍒嗗彂鐢熷湪2鐢靛瓙杩樺師闃舵銆傝繃姘у寲姘㈠叿鏈夋崯鍧忕數瑙ｈ川鑶滅殑浣滅敤锛屽簲灏介噺鎶戝埗杩囨哀鍖栨阿鐨勫舰鎴愩€傞搨閲戞槸鐩墠鍙嶅簲鏈€蹇殑鍌寲鍓傦紝浣嗗畠鏄竴绉嶇█鏈変笖鏄傝吹鐨勮吹閲戝睘銆傜洰鍓嶏紝浜轰滑姝ｅ湪绉瀬鐮旂┒鏇夸唬閾傞噾鐨勫偓鍖栧墏銆侟/span>
闃虫瀬
鍦ㄥ叾涓婂彂鐢熸哀鍖栧弽搴旂殑鐢垫瀬銆備篃绉颁负璐熸瀬銆傛垚涓洪槾鏋併€侟/span>
姘ф皵鏋?/span>
鐕冩枡鐢垫睜鐨勫彂鐢熸哀姘旇繕鍘熺殑鐢垫瀬銆傚叾涓洪槾鏋併€侟/span>
涔欓唶鐕冩枡鐢垫睜(DEFC)
闃虫瀬鍙嶅簲锛欳H3CH2OH+ 3H2O 鈫 2CO2+ 12H++ 12e
闃存瀬鍙嶅簲锛?O2+ 12H++ 12e 鈫 6H2O
鎬诲弽搴旓細CH3CH2OH + 3O2鈫 2CO2+ 3H2O
瀹為檯涓婏紝璇ュ弽搴旀湭鑳藉畬鍏ㄨ繘琛屽埌搴曪紝浠呰兘杩涜鍒颁骇鐢熶箼閰稿拰涔欓啗(4e涓烘)鐨勬楠ゃ€傚湪纰辨€ф潯浠朵笅
闃虫瀬鍙嶅簲锛欳H3CH2OH + 12OH-鈫 2CO2+ 9H2O + 12e
闃存瀬鍙嶅簲锛?O2+ 6 H2O + 12 e鈫?2 OH-
鎬讳綋鍙嶅簲 锛欳H3CH2OH+ 3O2鈫 2CO2+ 3H2O
鐒惰€岋紝鐩墠鐨勯槼鏋佸偓鍖栧墏杩樹笉鑳戒娇涓婅堪鍙嶅簲杩涜鍒板簳銆侟br/>CH3CH2OH+ 4OH-鈫扖H3COOH + 3H2O + 4e
闃存瀬
鍙戠敓杩樺師鍙嶅簲鐨勭數鏋併€備篃绉颁负姝ｆ瀬銆傛垚涓洪槼鏋併€侟/span>
YSZ
yttrium stabilized zirconia锛屾哀鍖栭攩閫氳繃娣诲姞閽囨潵绋冲畾銆傚湪楂樻俯涓嬬敤浣滄哀绂诲瓙瀵间綋鐨勫浐浣撶數瑙ｈ川銆備竴绉嶅浐浣撶數瑙ｈ川锛岀敱浜庡叾甯﹂殭杈冨ぇ锛屽叾鐢靛瓙鐢靛鐜囧彲浠ュ拷鐣ヤ笉璁★紝鐢ㄤ簬SOFCs涓€侟/span>
璐ㄥ瓙浼犲
鍦≒EMFC鍜孭AFC涓紝鐢辫川瀛愭惡甯︾數鑽枫€侟/span>
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