鍙嶅簲姒傝堪锛欬br/>

Chichibabin 鍙嶅簲锛岄綈榻愬反瀹惧弽搴旓紝鏄寚鍚″暥鐢ㄦ皑鍩洪挔澶勭悊鏃讹紝鍙戠敓姘ㄥ熀鍖栦綔鐢ㄧ敓鎴?-姘ㄥ熀鍚″暥鐨勫寲瀛﹀弽搴斻€傛鍙嶅簲鐢卞墠鑻忚仈鍖栧瀹堕綈榻愬反瀹句簬1914骞村彂鐜般€侟/span>

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鏈硶鏄湪鏉傜幆涓婂紩鍏ユ皑鍩虹殑绠€渚挎湁鏁堢殑鏂规硶锛屽箍娉涢€傜敤浜庡悇绉嶆爱鏉傝姵鐜紝濡傝嫰涓欏挭鍞戙€佸紓鍠瑰晧銆佸悥鍟跺拰鑿插暥绫诲寲鍚堢墿鍧囪兘鍙戠敓鏈弽搴斻€傚柟鍟夈€佸悺鍡€佸槯鍟躲€佸櫥鍞戠被鍖栧悎鐗╁弽搴旇緝涓哄洶闅俱€傛皑鍩哄寲璇曞墏闄ゆ皑鍩洪挔銆佹皑鍩洪捑澶栵紝杩樺彲浠ョ敤鍙栦唬鐨勭⒈閲戝睘姘ㄥ寲鐗┿€侟/span>

鍙嶅簲鏈虹悊锛欬/strong>

鍙嶅簲鏈虹悊杩樹笉鏄緢娓呮锛屽彲鑳芥槸鍚″暥涓庢皑鍩洪鍏堝姞鎴?鈪?锛?鈪?杞Щ涓€涓礋姘㈢瀛愮粰璐ㄥ瓙缁欎簣浣?AH)锛屼骇鐢熶竴鍒嗗瓙姘㈡皵鍜屽舰鎴愬皬閲忕殑2-姘ㄥ熀鍚″暥(鈪?锛屾灏忛噺鐨?鈪?鍙堝彲浠ヤ綔涓鸿川瀛愮殑缁欎簣浣擄紝鏈€鍚庣殑浜х墿鏄?-姘ㄥ熀鍚″暥鐨勯挔鐩愶紝鐢ㄦ按鍒嗚В寰楀埌2-姘ㄥ熀鍚″暥锛欬/span>

鍙嶅簲瀹炰緥锛欬/strong>

鍚″暥绫诲寲鍚堢墿涓嶆槗杩涜纭濆寲锛岀敤纭濆熀杩樺師娉曞埗澶囨皑鍩哄悺鍟剁敋涓哄洶闅俱€傛湰鍙嶅簲鏄湪鏉傜幆涓婂紩鍏ユ皑鍩虹殑绠€渚挎湁鏁堢殑鏂规硶锛屽箍娉涢€傜敤浜庡悇绉嶆爱鏉傝姵鐜紝濡傝嫰涓欏挭鍞戙€佸紓鍠瑰晧銆佸悥鍟跺拰鑿插暥绫诲寲鍚堢墿鍧囪兘鍙戠敓鏈弽搴斻€侟/span>

鍙傝€冩枃鐚細

[1] Elderfield, Heterocyclic Compounds, 1950, 1, 405.
[2] M. T. Leffler,Org. Reactions, 1942, 1, 91.
[3] A. E. Chichibabin, O.A. Zeide, J. Russ. Phys. Chem. Soc. 1914, 46,1216.
[4] J. Org. Chem., 1973, 38, 1974.
[5] R. C. Elderfield, Heterocyclic Compounds, 1950, I, 405.
[6] C. K. Ingold, Structure and Mechanism in Organic Chemistry, p809锛圠ondon,1953锛堻br/>[7] W.Kunz, H. Krauch, Chemiker Zig, 1958, 82, 802.