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位置: 首页> 品牌> Sigma-Aldrich> trans-Bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride

trans-Bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride

品牌
Sigma-Aldrich
CAS
1594112-87-4
货号
901126
包装型号
规格纯度
95%
价格
793.35 *本价格含增值税费
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半岛bd体育手机客户端 名称:
1594112-87-4
trans-Bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride
trans-(PBn 3) 2Ni( o-tolyl)Cl
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

应用

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2,however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.

其他说明

  • Technology Spotlight: Jamison Nickel (II) Precatalysts
  • A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

法律信息

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

基本信息

经验(实验)分子式 C49H49ClNiP2
分子量 794.01

半岛bd体育手机客户端 性质

质量水平 100
测定 95%
形式 powder or solid
reaction suitability reagent type: catalyst
mp 200-205 ℃
SMILES string Cl[Ni](C1=C(C)C=CC=C1)(P(CC2=CC=CC=C2)(CC3=CC=CC=C3)CC4=CC=CC=C4)P(CC5=CC=CC=C5)(CC6=CC=CC=C6)CC7=CC=CC=C7

安全信息

储存分类代码 13 - Non Combustible Solids
WGK WGK 3
闪点(F) Not applicable
闪点(C) Not applicable

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