半岛bd体育手机客户端 说明
一般描述
SnAP (Sn amino protocol) reagents have been developed by Professor Dr. Jeffrey Bode and co-workers. (These reagents are useful for the preparation of medium-ring (6-9 membered) saturatedN-heterocycles, including bicyclic and spirocyclic structures.) SnAP reagents are stable and easy to handle in laboratories. They can be prepared from simple raw materials.
应用
SnAP 3-Spiro-(4-Pip) M Reagent may be used in the preparation of unprotected, saturatedN-heterocyclic compounds.
SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturatedN-heterocycles. The synthesis ofN-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group
包装
500 mg in glass bottle
其他说明
Technology spotlight: SnAP Reagents
Professor product portal: Jeffrey Bode Research Group
SnAP Reagents for the Synthesis of Piperazines and Morpholines
SnAP reagents for the one-step synthesis of medium-ring saturatedN-heterocycles from aldehydes
SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of SaturatedN-Heterocycles
Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic SaturatedN-Heterocycles
基本信息
经验(实验)分子式 | C24H50N2O3Sn |
分子量 | 533.38 |
PubChem化学物质编号 | 329768846 |
NACRES | NA.22 |
半岛bd体育手机客户端 性质
质量水平 | 100 |
储存温度 | ?20℃ |
SMILES string | CCCC[Sn](CCCC)(COCC1(CCN(C(OC(C)(C)C)=O)CC1)N)CCCC |
InChI | 1S/C12H23N2O3.3C4H9.Sn/c1-11(2,3)17-10(15)14-7-5-12(13,6-8-14)9-16-4;3*1-3-4-2;/h4-9,13H2,1-3H3;3*1,3-4H2,2H3; |
InChI key | XZUSOLFDFJLEMZ-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H301 - H315 - H319 - H335 |
预防措施声明 | P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 |
危险分类 | Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
Sigma-Aldrich