SLAP TM

半岛bd体育手机客户端 说明

应用

When used with aliphatic or aromatic aldehydes, this silicon amine protocol (SLAP) reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)₂dtbbpy]PF₆((747769) is used with a recommended starting combination of Lewis acids Bi(OTf)₃(633305) and Cu(OTf)₂(283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions.

包装

500 mg in glass insert

其他说明

• Technology Spotlight: SLAP Reagents for Piperazine Synthesis
• Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
• Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.
• Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

基本信息

经验(实验)分子式	C6H17NSSi
分子量	163.36
NACRES	NA.22

半岛bd体育手机客户端 性质

质量水平	100
测定	≥95%
形式	liquid
折射率	n /D 1.4811
密度	0.90746 g/mL
储存温度	2-8℃
SMILES string	NCCSC[Si](C)(C)C

安全信息

储存分类代码	10 - Combustible liquids
WGK	WGK 3
闪点(F)	174.0 °F
闪点(C)	78.89 ℃