SLAP TA

半岛bd体育手机客户端 说明

应用

When used with aliphatic or aromatic aldehydes, this silicon amine protocol SLAP reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)₂dtbbpy]PF₆(747769) is used with a recommended starting combination of Lewis acids Bi(OTf)₃(633305) and Cu(OTf)₂(283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions.

包装

500 mg in amber glass bottle

其他说明

• Technology Spotlight: SLAP Reagents for Piperazine Synthesis
• Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
• Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.
• Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

基本信息

经验(实验)分子式	C7H19NSSi
分子量	177.38
NACRES	NA.22

半岛bd体育手机客户端 性质

质量水平	100
测定	95%
形式	liquid
密度	0.90452
储存温度	2-8℃

安全信息

象形图
警示用语：	Warning
危险声明	H226
预防措施声明	P210 - P370 + P378
危险分类	Flam. Liq. 3
储存分类代码	3 - Flammable liquids
WGK	WGK 3
闪点(F)	75.0 °F
闪点(C)	23.89 ℃