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位置: 首页> 品牌> Sigma-Aldrich> SLAPN-Bn-3Me-Pip Reagent

SLAPN-Bn-3Me-Pip Reagent

品牌
Sigma-Aldrich
CAS
2168413-62-3
货号
900406
包装型号
规格纯度
价格
904.34 *本价格含增值税费
促销
服务
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数量
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半岛bd体育手机客户端 名称:
2168413-62-3
SLAP N-Bn-3Me-Pip Reagent
( S)- N1-Benzyl- N1-((trimethylsilyl)methyl)propane-1,2-diamine
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

应用

Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, form N-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)2dtbbpy]PF6(747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis.

包装

500 mg in amber glass bottle

其他说明

  • Technology Spotlight: SLAP Reagents for Piperazine Synthesis
  • Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
  • Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.
  • Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

基本信息

经验(实验)分子式 C14H26N2Si
分子量 250.46

半岛bd体育手机客户端 性质

质量水平 100
储存温度 ?20℃

安全信息

象形图 GHS07
警示用语: Warning
危险声明 H315 - H319 - H335
预防措施声明 P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类 Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官 Respiratory system
储存分类代码 10 - Combustible liquids
WGK WGK 3
闪点(F) Not applicable
闪点(C) Not applicable

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