半岛bd体育手机客户端 说明
应用
Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, formN-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)2dtbbpy]PF6(747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis.
包装
500 mg in glass bottle
其他说明
基本信息
经验(实验)分子式 | C13H24N2Si |
分子量 | 236.43 |
PubChem化学物质编号 | 329769827 |
NACRES | NA.22 |
半岛bd体育手机客户端 性质
质量水平 | 100 |
测定 | 95% |
形式 | liquid (paste) |
折射率 | n
|
密度 | 0.9366 g/mL |
储存温度 | ?20℃ |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H315 - H319 - H335 |
预防措施声明 | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 10 - Combustible liquids |
WGK | WGK 3 |
闪点(F) | 198.0 °F |
闪点(C) | 92.2 ℃ |
Sigma-Aldrich