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位置: 首页> 品牌> Sigma-Aldrich> SLAP 2,3-Bicyclo-(3,4-THF)N-BnPip Reagent

SLAP 2,3-Bicyclo-(3,4-THF)N-BnPip Reagent

品牌
Sigma-Aldrich
货号
900401
包装型号
规格纯度
≥95%
价格
1373.81 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
- +
半岛bd体育手机客户端 名称:
SLAP 2,3-Bicyclo-(3,4-THF) N-BnPip Reagent
trans- N 3-Benzyl- N 3-((trimethylsilyl)methyl)tetrahydrofuran-3,4-diamine
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

应用

Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, formN-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)2dtbbpy]PF6(747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis.

包装

500 mg in amber glass bottle

其他说明

  • Technology Spotlight: SLAP Reagents for Piperazine Synthesis
  • Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
  • Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.
  • Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

基本信息

经验(实验)分子式 C15H26N2OSi
分子量 278.47
NACRES NA.22

半岛bd体育手机客户端 性质

质量水平 100
测定 ≥95%
形式 liquid
折射率 n /D 1.520
密度 1.000 g/mL
储存温度 ?20℃

安全信息

象形图 GHS07
警示用语: Warning
危险声明 H315 - H319 - H335
预防措施声明 P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类 Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官 Respiratory system
储存分类代码 10 - Combustible liquids
WGK WGK 3

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