半岛bd体育手机客户端 说明
一般描述
Non-fullerene acceptors (NFAs) are currently a major focus of research in the development of bulk-heterojunction organic solar cells (OSCs). In contrast to the widely used fullerene acceptors (FAs), the optical properties and electronic energy levels of NFAs can be designed and readily tuned. NFA-based OSCs can also achieve greater thermal stability and photochemical stability, as well as longer device lifetimes, than their FA-based counterparts.Recent developments have led to a rapid increase in power conversion efficiencies for NFA OSCs, with values now exceeding 15% in a single junction cell, and >17% for a tandem cell, demonstrating the viability of using NFAs to replace FAs in next-generation high-performance OSCs.
应用
F-M is a non-fullerene acceptor that absorbs visible light, when used in a front cell paired with NIR absorbing rear cell, the resulted tandem organic solar cell gave a record energy conversion efficiency of 17.3%.
Tandem Cell Device performance:
ITO/ZnO/PFN-Br/PBDB-T:F-M/M-PEDOT/ZnO/PTB7- Th:O6T-4F:PC71BM/MoO3/Ag
Voc=1.642 V
Jsc=14.35 mA/cm2
FF=73.7%
PCE=17.3%
基本信息
经验(实验)分子式 | C99H122N4O2S2 |
分子量 | 1464.18 |
半岛bd体育手机客户端 性质
描述 | Band gap: 1.72 eV Band gap: Eg= 1.72 eV Solubility: Soluble in Chloroform, CB and ODCB |
测定 | ≥98% |
形式 | solid |
轨道能量 | HOMO -5.42 eV LUMO -3.70 eV |
安全信息
储存分类代码 | 11 - Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
Sigma-Aldrich