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位置: 首页> 品牌> Sigma-Aldrich> Endo-Phenyl Kwon [2.2.1] Bicyclic Phosphine

Endo-Phenyl Kwon [2.2.1] Bicyclic Phosphine

品牌
Sigma-Aldrich
货号
798363
包装型号
规格纯度
95% (HPLC)
价格
1346.47 *本价格含增值税费
促销
服务
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数量
- +
半岛bd体育手机客户端 名称:
Endo-Phenyl Kwon [2.2.1] Bicyclic Phosphine
(1 S,4 S,5 S)-5-(phenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

应用

The bicyclic, chiral phosphine was developed by the Kwon Research Group.Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.

包装

100 mg in clear glass bottle

其他说明

Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (-)-Pyrrolines

Technology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from Hydroxyproline

Aldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations

基本信息

经验(实验)分子式 C18H20NO2PS
分子量 345.40
MDL编号 MFCD28016350
PubChem化学物质编号 329768643
NACRES NA.22

半岛bd体育手机客户端 性质

质量水平 100
测定 95% (HPLC)
形式 powder
储存条件 under inert gas
mp 96-101 ℃
储存温度 2-8℃
SMILES string O=S(N1C[C@@]2([H])[P@@](C3=CC=CC=C3)C[C@]1([H])C2)(C4=CC=C(C)C=C4)=O
InChI 1S/C18H20NO2PS/c1-14-7-9-18(10-8-14)23(20,21)19-12-17-11-15(19)13-22(17)16-5-3-2-4-6-16/h2-10,15,17H,11-13H2,1H3/t15-,17-,22?/m0/s1
InChI key BWXYDSDVFPJTFY-TWMUNHRGSA-N

安全信息

象形图 GHS07
警示用语: Warning
危险声明 H302
预防措施声明 P301 + P312 + P330
危险分类 Acute Tox. 4 Oral
储存分类代码 13 - Non Combustible Solids
WGK WGK 3
闪点(F) Not applicable
闪点(C) Not applicable

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