Endo-1-Naphthyl Kwon [2.2.1] Bicyclic Phosphine

品牌

Sigma-Aldrich

货号

798436

包装型号

100 MG

规格纯度

价格

829.26 元 *本价格含增值税费

促销

数量

- +

半岛bd体育手机客户端名称：

Endo-1-Naphthyl Kwon [2.2.1] Bicyclic Phosphine
(1 S,4 S,5 S)-5-(naphthalen-1-yl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane

半岛bd体育手机客户端介绍：

半岛bd体育手机客户端说明

应用

The bicyclic, chiral phosphine was developed by the Kwon Research Group. Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.

包装

100 mg in glass bottle

其他说明

Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (-)-Pyrrolines

Technology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from Hydroxyproline

Aldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations

基本信息

经验(实验)分子式	C₂₂H₂₂NO₂PS
分子量	395.45
PubChem化学物质编号	329768649
NACRES	NA.22

半岛bd体育手机客户端性质

形式	powder
质量水平	100
储存条件	under inert gas
储存温度	2-8℃
SMILES string	O=S(N1C[C@H]2[P@@](C3=CC=CC4=C3C=CC=C4)C[C@@H]1C2)(C5=CC=C(C)C=C5)=O
InChI	1S/C22H22NO2PS/c1-16-9-11-20(12-10-16)27(24,25)23-14-19-13-18(23)15-26(19)22-8-4-6-17-5-2-3-7-21(17)22/h2-12,18-19H,13-15H2,1H3
InChI key	RGHUOMJULXTHPX-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable