半岛bd体育手机客户端 说明

应用

Reactant for asymmetric:

• Allylic substitution
• Intermolecular Pauson-Khand reaction of symmetrically substituted alkynes
• Hydrogenation
• Intramolecular α-arylation of aldehydes

Reactant for:

• Alcoholysis of phosphane-boranes
• Probing hemilabile sites of Bis(phosphine) monoxide ligands

包装

250 mg in glass bottle

基本信息

经验(实验)分子式	C14H14ClO2P
分子量	280.69
MDL编号	MFCD04972301
PubChem化学物质编号	329761258
NACRES	NA.22

半岛bd体育手机客户端 性质

质量水平	100
测定	95%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand
mp	62-66 ℃
官能团	phosphine
SMILES string	COc1ccc(cc1)P(Cl)c2ccc(OC)cc2
InChI	1S/C14H14ClO2P/c1-16-11-3-7-13(8-4-11)18(15)14-9-5-12(17-2)6-10-14/h3-10H,1-2H3
InChI key	YTFQUBRFOJIJOZ-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
危险分类	Skin Corr. 1B
储存分类代码	8A - Combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges