半岛bd体育手机客户端 说明
一般描述
2-(Trimethylsilyl)-2-cyclohexen-1-one is a silyl enone.
应用
The following silyl enone can be converted into a highly useful cyclohexyne precursor as reported by the Garg and DuBois groups. The resulting silyltriflate adduct can be subjected to various dienes and dipolarophiles in the presence of Cesium Fluoride.
包装
500 mg in glass bottle
其他说明
Cycloadditions of Cyclohexynes and Cyclopentyne
Modular synthesis of the pentacyclic core of batrachotoxin and select batrachotoxin analogue designs
基本信息
经验(实验)分子式 | C9H16OSi |
分子量 | 168.31 |
MDL编号 | MFCD11502410 |
PubChem化学物质编号 | 329768917 |
NACRES | NA.22 |
半岛bd体育手机客户端 性质
描述 | Fp: 15.8°F |
质量水平 | 100 |
形式 | liquid |
折射率 | n
|
密度 | 0.8680 g/mL at 25 ℃ |
储存温度 | ?20℃ |
SMILES string | O=C1C([Si](C)(C)C)=CCCC1 |
InChI | 1S/C9H16OSi/c1-11(2,3)9-7-5-4-6-8(9)10/h7H,4-6H2,1-3H3 |
InChI key | SXGCQSJRVVKTOH-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H228 - H302 |
预防措施声明 | P210 - P301 + P312 + P330 - P370 + P378 |
危险分类 | Acute Tox. 4 Oral - Flam. Sol. 2 |
储存分类代码 | 4.1B - Flammable solid hazardous materials |
WGK | WGK 3 |
闪点(F) | 15.8 °F |
闪点(C) | -9 ℃ |
Sigma-Aldrich