半岛bd体育手机客户端 名称：
213343-64-7
1,2-Bis[(2
S,5
S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
(
S,
S)-Et-DUPHOS-Rh
1,2-双[(2
S,5
S)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I)
半岛bd体育手机客户端 介绍：
半岛bd体育手机客户端 说明
应用
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
Catalyst for:
- Preparation of a key unit B precursor of cryptophycins via Horner-Wadsworth-Emmons reaction and asymmetric hydrogenation
- Preparation of constrained phenylalanine analogs via Heck reaction followed by asymmetric hydrogenation and cyclization steps
- Enantioselective preparation of N-benzyloxy-β-amino acid Me esters by hydrogenation of α-(benzyloxyaminomethyl)acrylate stereoisomers
- Preparation of fluoro amino acids as synthons for potent macrocyclic HCV NS3 protease inhibitors
- Stereoselective preparation of triply isotope-labeled Ser, Cys, and Ala
- Preparation of β-amino acids from asymmetric hydrogenation of α-(aminomethyl)acrylates
- Asymmetric hydrogenation of a-primary and secondary amino ketones and asymmetric synthesis of (-)-arbutamine and (-)-denopamine
包装
50, 250 mg in amber glass bottle
法律信息
与 Kanata Chemical Technologies Inc. 联合销售，仅供研究使用。这些化合物由 E.I. du Pont de Nemours and Company 授权制造和销售，此许可不包括利用这些化合物制备在制药领域销售的半岛bd体育手机客户端 的权利。
基本信息
| 经验(实验)分子式 |
C30H48BF4P2Rh |
| 分子量 |
660.36 |
| PubChem化学物质编号 |
329761249 |
| NACRES |
NA.22 |
半岛bd体育手机客户端 性质
| 形式 |
powder |
| SMILES string |
[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.CC[C@H]2CC[C@H](CC)P2c3ccccc3P4[C@@H](CC)CC[C@@H]4CC |
| InChI |
1S/C22H36P2.C8H12.BF4.Rh/c1-5-17-13-14-18(6-2)23(17)21-11-9-10-12-22(21)24-19(7-3)15-16-20(24)8-4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h9-12,17-20H,5-8,13-16H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t17-,18-,19-,20-;;;/m0.../s1 |
| InChI key |
DSYBEQKPSKLNMC-ZCTOJWETSA-N |
安全信息
| 储存分类代码 |
11 - Combustible Solids |
| WGK |
WGK 3 |
| 闪点(F) |
Not applicable |
| 闪点(C) |
Not applicable |
| 个人防护装备 |
Eyeshields, Gloves, type N95 (US) |
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