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(S)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-disulfonimide

(S)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-disulfonimide

品牌
Sigma-Aldrich
CAS
1242421-77-7
货号
790761
包装型号
规格纯度
95%
价格
3620.93 *本价格含增值税费
促销
服务
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  • 包邮
  • 增值税票
数量
- +
半岛bd体育手机客户端 名称:
1242421-77-7
( S)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-disulfonimide
(11bS)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine 3,3,5,5-tetraoxide
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

应用

Chiral Bronsted acid demonstrated in Mukaiyama aldol reactions and Friedel-Crafts alkylation of indoles with sulfonyl imines.

A Powerful Chiral Counteranion Motif for Asymmetric Catalysis

Chiral Sulfonimide as a Br?nsted Acid Organocatalyst for Asymmetric Friedel-Crafts Alkylation of Indoles with Imines

Chiral N-Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination

包装

100 mg in clear glass bottle
500 mg in amber glass bottle

基本信息

经验(实验)分子式 C36H17F12NO4S2
分子量 819.64
MDL编号 MFCD28009151
PubChem化学物质编号 329768238
NACRES NA.22

半岛bd体育手机客户端 性质

测定 95%
reaction suitability reaction type: Aldol Reaction
reaction type: Allylation
reaction type: Carbonyl/Imine Addition
reaction type: Friedel-Crafts Alkylation
mp 325-330 ℃
SMILES string O=S(C1=C(C2=C(C=CC=C3)C3=CC(C4=CC(C(F)(F)F)=CC(C(F)(F)F)=C4)=C2S5(=O)=O)C6=C(C=CC=C6)C=C1C7=CC(C(F)(F)F)=CC(C(F)(F)F)=C7)(N5)=O
InChI 1S/C36H17F12NO4S2/c37-33(38,39)21-9-19(10-22(15-21)34(40,41)42)27-13-17-5-1-3-7-25(17)29-30-26-8-4-2-6-18(26)14-28(32(30)55(52,53)49-54(50,51)31(27)29)20-11-23(35(43,44)45)16-24(12-20)36(46,47)48/h1-16,49H
InChI key DFXCMPXSCANWFA-UHFFFAOYSA-N

安全信息

储存分类代码 11 - Combustible Solids
WGK WGK 3
闪点(F) Not applicable
闪点(C) Not applicable

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