(<i>R</i>,<i>S</i>)-Bode Kinetic Resolution Catalyst

(R,S)-Bode Kinetic Resolution Catalyst

品牌

Sigma-Aldrich

CAS

1394957-71-1

货号

804568

包装型号

100 MG

规格纯度

价格

947 元 *本价格含增值税费

促销

数量

- +

半岛bd体育手机客户端名称：

1394957-71-1
( R, S)-Bode Kinetic Resolution Catalyst
(4a R,9a S)-6-Bromo-4-hydroxy-4,4 a,9,9a-tetrahydroindeno[2,1- b][1,4]oxazin-3(2 H)-one

半岛bd体育手机客户端介绍：

半岛bd体育手机客户端说明

应用

The following hydroxamic acid catalyst was shown by Bode and coworkers to assist in the kinetic resolution of cyclic amines through acylation of one enantiomer, which can be controlled using either the (RorS)- or (SorR)-Bode Kinetic Resolution Catalyst, both of which are also available through sigma-aldrich.
It can also be employed in the preparation of nonracemic piperidines by kinetic resolution using an α-hydroxy-α′, β-unsaturated ketone in the presence of a pyrrolotriazolium salt.

包装

100 mg in glass bottle

其他说明

Expanded substrate scope and catalyst optimization for the catalytic kinetic resolution ofN-heterocycles

基本信息

经验(实验)分子式	C₁₁H₁₀BrNO₃
分子量	284.11
PubChem化学物质编号	329768882
NACRES	NA.22

半岛bd体育手机客户端性质

质量水平	100
储存温度	15-25℃
SMILES string	O=C(CO1)N(O)[C@@]2([H])[C@]1([H])CC3=CC=C(Br)C=C32
InChI	1S/C11H10BrNO3/c12-7-2-1-6-3-9-11(8(6)4-7)13(15)10(14)5-16-9/h1-2,4,9,11,15H,3,5H2/t9-,11+/m0/s1
InChI key	FQXSUQCCAHKURK-GXSJLCMTSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H302
预防措施声明	P301 + P312 + P330
危险分类	Acute Tox. 4 Oral
储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable