半岛bd体育手机客户端 说明
应用
(Ir[Me(Me)ppy]2(dtbpy))PF6or Ir(dmppy)2(dtbbpy)PF6is an iridium photoredox catalyst that facilitates a variety of transformations using visible light, including the α- and β-alkylation of aldehydes.
其他说明
Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis
Direct, enantioselective α-alkylation of aldehydes using simple olefins
基本信息
| 经验(实验)分子式 | C44H48F6IrN4P |
| 分子量 | 970.06 |
半岛bd体育手机客户端 性质
| 形式 | powder |
| reaction suitability | core: iridium reagent type: catalyst reaction type: Photocatalysis |
| photocatalyst activation | 465 nm |
| SMILES string | F[P-](F)(F)(F)(F)F.CC1=CC([Ir+]([N]2=C3C=C(C)C=C2)(C4=C5C=CC(C)=C4)([N]6=C7C=C(C(C)(C)C)C=C6)([N]8=C7C=C(C(C)(C)C)C=C8)[N]9=C5C=C(C)C=C9)=C3C=C1 |
安全信息
| 储存分类代码 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
Sigma-Aldrich
m.cnreagent.com
