半岛bd体育手机客户端 说明
一般描述
(η5-Cyclopentadienyl)[N,N-dimethyl-N′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate is also referred to as Herzon reductive hydration catalyst. Herzon reductive hydration catalyst is a half-sandwich ruthenium complex. It is a tridentate nitrogen-based ligand containing a hemilabile 3-(dimethylamino)propyl group. It participates in the conversion of terminal alkynes to linear alcohols.
应用
Catalyst mediates the transformation of alkynes to alcohols through ananti-Markovnikov addition. This reaction occurs at room temperature with the use of formic acid to assist in the reduction of the intermediate aldehyde to the corresponding alcohol.
包装
100 mg in glass bottle
其他说明
A Highly Active and Air-Stable Ruthenium Complex for the Ambient TemperatureAnti-Markovnikov Reductive Hydration of Terminal Alkynes
基本信息
| 经验(实验)分子式 | C16H22F6N3PRu |
| 分子量 | 502.40 |
| PubChem化学物质编号 | 329768426 |
| NACRES | NA.22 |
半岛bd体育手机客户端 性质
| 形式 | powder |
| reaction suitability | core: ruthenium reagent type: catalyst |
| mp | >180 ℃ |
| SMILES string | CN(C)CCC/N=C/C1=NC=CC=C1.F[P-](F)(F)(F)(F)F.[C]2[C][C][C][C]2.[Ru+] |
| InChI | 1S/C11H17N3.C5H5.F6P.Ru/c1-14(2)9-5-7-12-10-11-6-3-4-8-13-11;1-2-4-5-3-1;1-7(2,3,4,5)6;/h3-4,6,8,10H,5,7,9H2,1-2H3;1-5H;;/q;;-1;+1/b12-10+;;; |
| InChI key | KUSUXOOKLDLSSI-AKMNYRKMSA-N |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H315 - H319 - H335 |
| 预防措施声明 | P302 + P352 - P305 + P351 + P338 |
| 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 11 - Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
Sigma-Aldrich
m.cnreagent.com
