(4<I>S</I>)-2-[2-(二苯基膦)苯基]-4,5-二氢-5,5-二甲基-4-(1-甲基乙基)-噁唑

(4S)-2-[2-(二苯基膦)苯基]-4,5-二氢-5,5-二甲基-4-(1-甲基乙基)-噁唑

品牌

Sigma-Aldrich

CAS

1152313-76-2

货号

719641

包装型号

500 MG, 97%

规格纯度

97%

价格

1804.71 元 *本价格含增值税费

促销

数量

- +

半岛bd体育手机客户端名称：

1152313-76-2
(4 S)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-5,5-dimethyl-4-(1-methylethyl)-oxazole
( S)-5,5-(Dimethyl)-i-Pr-PHOX
( S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-5,5-dimethyl-4,5-dihydrooxazole
(4 S)-2-[2-(二苯基膦)苯基]-4,5-二氢-5,5-二甲基-4-(1-甲基乙基)-噁唑
( S)-2-(2-(二苯基膦)苯基)-4-异丙基-5,5-二甲基-4,5-二氢噁唑
( S)-5,5-(二甲基)-i-Pr-PHOX

半岛bd体育手机客户端介绍：

半岛bd体育手机客户端说明

应用

Use of 5,5-(Dimethyl)-i-Pr-PHOX as a Practical Equivalent to t-Bu-PHOX in Asymmetric Catalysis

Design, Synthesis, and Applications of Potential Substitutes of t-Bu-Phosphinooxazoline in Pd-Catalyzed Asymmetric Transformations and Their Use for the Improvement of the Enantioselectivity in the Pd-Catalyzed Allylation Reaction of Fluorinated Allyl Enol Carbonates
(S)-5,5-(Dimethyl)-i-Pr-PHOX is a phosphinooxazoline ligand (PHOX), belongs to the class of non-C₂symmetric chiral ligand.
It can be used in:

The enantioselective Pd-catalyzed allylation reactions.
The synthesis of (R)-2-phenyl-2,5-dihydrofuran by the enantioselective Heck reaction between 2,3-dihydrofuran and phenyl triflate.
The allylation reaction of fluorinated allyl enol carbonates and fluorinated silyl enol ethers to prepare allylated tert α-fluoroketones.

包装

500 mg in glass bottle

基本信息

经验(实验)分子式	C₂₆H₂₈NOP
分子量	401.48
MDL编号	MFCD16621462
PubChem化学物质编号	329763666
NACRES	NA.22

半岛bd体育手机客户端性质

测定	97%
mp	124-128 ℃
SMILES string	CC(C)[C@@H]1N=C(OC1(C)C)c2ccccc2P(c3ccccc3)c4ccccc4
InChI	1S/C26H28NOP/c1-19(2)24-26(3,4)28-25(27-24)22-17-11-12-18-23(22)29(20-13-7-5-8-14-20)21-15-9-6-10-16-21/h5-19,24H,1-4H3/t24-/m0/s1
InChI key	JGUZEKBWCGNHHN-DEOSSOPVSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H301 - H315 - H319 - H335 - H413
预防措施声明	P273 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338
危险分类	Acute Tox. 3 Oral - Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

(4S)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-5,5-dimethyl-4-(1-methylethyl)-oxazole

(4S)-2-[2-(二苯基膦)苯基]-4,5-二氢-5,5-二甲基-4-(1-甲基乙基)-噁唑