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位置: 首页> 品牌> Sigma-Aldrich> (2R)-2-Phenyl-3,4-dihydro-2H-pyrimido[2,1-b][1,3]benzothiazole

(2R)-2-Phenyl-3,4-dihydro-2H-pyrimido[2,1-b][1,3]benzothiazole

品牌
Sigma-Aldrich
CAS
1316861-19-4
货号
901233
包装型号
规格纯度
≥95%
价格
1781.35 *本价格含增值税费
促销
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数量
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半岛bd体育手机客户端 名称:
1316861-19-4
(2 R)-2-Phenyl-3,4-dihydro-2 H-pyrimido[2,1-b][1,3]benzothiazole
( R)-Homobenzotetramisole
( R)-2-Phenyl-3,4-dihydro-2 H-benzo[4,5]thiazolo[3,2- a]pyrimidine
Birman ( R)-HBTM
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

应用

This chiral isothiourea homobenzotetramisole ((R)-HBTM) developed by the Birman lab is an organocatalyst that has been used for kinetic resolution, determination of absolute configuration, and nucleophile-catalysed, Michael–aldol-b-lactonization (NCMAL). This same product was previously listed as L511730, and the complementary (S)-HBTM organocatalyst (900542) is also available.

其他说明


Technology Spotlight: Homobenzotetramisole (HBTM): A General Organocatalyst for Asymmetric Acylations

[1] Determination of the Absolute Configuration β-Chiral Primary Alcohols Using the Competing Enantioselective Conversion Method

[2] Asymmetric Catalytic Synthesis of Thiochromenes via an Acyl Transfer-Initiated Cascade

[3] Rapid assembly of complex cyclopentanes employing chiral, α, β-unsaturated acylammonium intermediates

[4] Determination of Absolute Configuration Using Kinetic Resolution Catalysts

[5] Kinetic Resolution of Secondary Alcohols Using Amidine-Based Catalysts

基本信息

经验(实验)分子式 C16H14N2S
分子量 266.36
MDL编号 MFCD26793803

半岛bd体育手机客户端 性质

质量水平 100
测定 ≥95%
形式 powder or chunks
mp 145-147 ℃
储存温度 2-8℃
SMILES string C12=CC=CC=C1SC3=N[C@@H](C4=CC=CC=C4)CCN23
InChI 1S/C16H14N2S/c1-2-6-12(7-3-1)13-10-11-18-14-8-4-5-9-15(14)19-16(18)17-13/h1-9,13H,10-11H2/t13-/m1/s1
InChI key ZMYZJAQMQBHNLH-CYBMUJFWSA-N

安全信息

储存分类代码 13 - Non Combustible Solids
WGK WGK 3
闪点(F) Not applicable
闪点(C) Not applicable

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