(1S,4S,8S)-5-苄基-8-甲氧基-1,8-二甲基-2-(2′-甲基丙基)-双环[2.2.2]辛-2,5-二烯

品牌

Sigma-Aldrich

CAS

862499-50-1

货号

709492

包装型号

100 MG, 97%

规格纯度

97%

价格

2219.84 元 *本价格含增值税费

促销

数量

- +

半岛bd体育手机客户端名称：

862499-50-1
(1 S,4 S,8 S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene
(1 S,4 S,8 S)--5-Benzyl-8-methoxy-1,8-dimethyl-2-(2′-methylpropyl)-bicyclo[2.2.2]octa-2,5-diene
(1 S,4 S,8 S) Carreira DOLEFIN Ligand
(1 S,4 S,8 S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethyl-2-bicyclo[2.2.2]octa-2,5-diene
(1 S,4 S,8 S)-5-苄基-8-甲氧基-1,8-二甲基-2-(2′-甲基丙基)-双环[2.2.2]辛-2,5-二烯
(1 S,4 S,8 S)-5-苄基-2-异丁基-8-甲氧基-1,8-二甲基-2-双环[2.2.2]辛-2,5-二烯
(1 S,4 S,8 S) Carreira DOLEFIN 配体

半岛bd体育手机客户端介绍：

半岛bd体育手机客户端说明

一般描述

(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene, an enantiopure diene ligand developed by Carreira, is most commonly used in asymmetric catalysis. It is generally prepared from commercially available (R)-carvone.

应用

Carreira DOLEFIN Ligands
(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene is mainly useful for the stereoselective synthesis of diarylmethine stereogenic centers.

包装

100 mg in clear glass bottle

基本信息

经验(实验)分子式	C₂₂H₃₀O
分子量	310.47
MDL编号	MFCD09265063
PubChem化学物质编号	329762875

半岛bd体育手机客户端性质

测定	97%
形式	liquid
旋光性	[α]/D ?84±5°, c = 0.5 in chloroform
reaction suitability	reaction type: click chemistry
折射率	n 20/D 1.522
SMILES string	CO[C@@]1(C)C[C@@]2(C)C=C(Cc3ccccc3)[C@@H]1C=C2CC(C)C
InChI	1S/C22H30O/c1-16(2)11-19-13-20-18(12-17-9-7-6-8-10-17)14-21(19,3)15-22(20,4)23-5/h6-10,13-14,16,20H,11-12,15H2,1-5H3/t20-,21+,22-/m0/s1
InChI key	ACWLDJOHMGJACE-BDTNDASRSA-N

安全信息

储存分类代码	12 - Non Combustible Liquids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable