半岛bd体育手机客户端 说明

一般描述

2-Naphthalenyl ester fluorosulfuric acid is a diaryl fluorosulfate (diaryl-OSO₂F). It can be synthesized with 99% yield from the reaction between phenol and sulfuryl fluoride in the presence of triethylamine. It undergoes Suzuki-Miyaura reaction with aryl boronic acid in the presence of Pd(OAc)₂and Et₃N to afford the corresponding biaryl derivative.

应用

The following aryl fluorosulfate can be utilized as a cross-coupling partner in Suzuki-Miyaura reactions. The standard reaction conditions for these palladium-catalyzed C-C bond formations are ligand-free and can be performed in water, at room temperature and are not air sensitive.

包装

500 mg in glass bottle

其他说明

Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates

基本信息

经验(实验)分子式	C10H7FO3S
分子量	226.22
PubChem化学物质编号	329772675
NACRES	NA.22

半岛bd体育手机客户端 性质

形式	powder
质量水平	100
SMILES string	O=S(OC1=CC=C2C(C=CC=C2)=C1)(F)=O
InChI	1S/C10H7FO3S/c11-15(12,13)14-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H
InChI key	IJQQGAGYVGLLJL-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类	Skin Corr. 1B
储存分类代码	8B - Non-combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable