半岛bd体育手机客户端 名称:
887144-97-0
3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
Togni’s Reagent
3,3-二甲基-1-(三氟甲基)-1,2-苯并碘氧杂戊环
Togni 试剂
1,3-二氢-3,3-二甲基-1-(三氟甲基)-1,2-苯并碘氧杂戊环
半岛bd体育手机客户端 介绍:
半岛bd体育手机客户端 说明
应用
- Selective trifluoromethylation of 1,3-disubstituted arenes through iridium-catalyzed arene borylation and copper-catalyzed trifluoromethylation
- Copper-catalyzed trifluoromethylation of aryl- and alkenylboronic acids with electrophilic trifluoromethylating reagent
- Pd-catalyzed electrophilic ortho-trifluoromethylation of arenes using trifluoroacetic acid as a promotor
Used in the Preparation of
- Trifluoromethylimidoylethyl substituted heterocycles via bis(trifluoromethylsulfonyl)amine-catalyzed Rotter type reaction of heterocycles with nitriles in presence of trifluoromethylbenziodoxole
- Stereoselective synthesis of α-trifluoromethyl aldehydes via trimethylbenzylimidazolidinone and copper-catalyzed enantioselective α-trifluoromethylation of aldehydes with iodonium salts
包装
100 mg in clear glass bottle
500 mg in amber glass bottle
基本信息
经验(实验)分子式 |
C10H10F3IO |
分子量 |
330.09 |
MDL编号 |
MFCD10567056 |
PubChem化学物质编号 |
329766407 |
NACRES |
NA.22 |
半岛bd体育手机客户端 性质
质量水平 |
100 |
测定 |
98% |
mp |
75-79 ℃ |
储存温度 |
2-8℃ |
SMILES string |
CC1(C)O[I](c2ccccc12)C(F)(F)F |
InChI |
1S/C10H10F3IO/c1-9(2)7-5-3-4-6-8(7)14(15-9)10(11,12)13/h3-6H,1-2H3 |
InChI key |
HVAPLSNCVYXFDQ-UHFFFAOYSA-N |