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位置: 首页> 品牌> Sigma-Aldrich> 双(3,5-二(三氟甲基)苯基)氯膦

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine

双(3,5-二(三氟甲基)苯基)氯膦

品牌
Sigma-Aldrich
CAS
142421-57-6
货号
694746
包装型号
规格纯度
价格
568.63 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
- +
半岛bd体育手机客户端 名称:
142421-57-6
Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine
P,P-Bis[3,5-bis(trifluoromethyl)phenyl]phosphinous chloride
双(3,5-二(三氟甲基)苯基)氯膦
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

应用

Reactant for synthesis of:

  • Chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation
  • Ligands for palladium-catalyzed stereoselective allylation reactions
  • Ligands for enantioselective hydrogenations
  • Josiphos analog as catalyst for asymmetric hydrogenation
  • Ligands used in asymmetric hydrovinylation reactions

Reactant for enantioselective hydrogenation reactions catalyzed by Ru-(phosphine-oxazoline) complexes

包装

100, 500 mg in glass bottle

基本信息

经验(实验)分子式 C16H6ClF12P
分子量 492.63
MDL编号 MFCD01630852
PubChem化学物质编号 329761683
NACRES NA.22

半岛bd体育手机客户端 性质

reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
质量水平 100
mp 25-29 ℃
官能团 phosphine
SMILES string FC(F)(F)c1cc(cc(c1)C(F)(F)F)P(Cl)c2cc(cc(c2)C(F)(F)F)C(F)(F)F
InChI 1S/C16H6ClF12P/c17-30(11-3-7(13(18,19)20)1-8(4-11)14(21,22)23)12-5-9(15(24,25)26)2-10(6-12)16(27,28)29/h1-6H
InChI key DFZQEHBNAJGDCT-UHFFFAOYSA-N

安全信息

象形图 GHS02GHS05
警示用语: Danger
危险声明 H261 - H314
预防措施声明 P231 + P232 - P280 - P305 + P351 + P338 - P310 - P422
危险分类 Skin Corr. 1B - Water-react. 3
储存分类代码 4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK WGK 3
闪点(F) Not applicable
闪点(C) Not applicable
个人防护装备 Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

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