[(S,S)-Teth-TsDpen RuCl]

半岛bd体育手机客户端 说明

应用

[(S,S)-Teth-TsDpen RuCl] is a catalyst for the asymmetric hydrogenation of ketones. It can be used as a catalyst:

• In the reduction of a ketone intermediate for the synthesis of esketamine.
• In asymmetric hydrogenation of acetylenic ketones.
• For the preparation of (3S,6S)-1,8-diphenylocta-1,7-diyne-3,6-diol starting from 1,8-diphenylocta-1,7-diyne-3,6-dione.

包装

100 mg in clear glass bottle
500 mg in amber glass bottle

基本信息

经验(实验)分子式	C30H31ClN2O2RuS
分子量	620.17
PubChem化学物质编号	329766311
NACRES	NA.22

半岛bd体育手机客户端 性质

旋光性	[α]22/D +339°, c = 0.5% in chloroform
质量水平	100
reaction suitability	core: ruthenium reagent type: catalyst
mp	260-268 ℃
储存温度	2-8℃
SMILES string	Cc1ccc(cc1)S(=O)(=O)N2[C@H]([C@@H]([N@@H](CCCc3ccccc3)[Ru]2Cl)c4ccccc4)c5ccccc5
InChI	1S/C30H31N2O2S.ClH.Ru/c1-24-19-21-28(22-20-24)35(33,34)32-30(27-17-9-4-10-18-27)29(26-15-7-3-8-16-26)31-23-11-14-25-12-5-2-6-13-25;;/h2-10,12-13,15-22,29-31H,11,14,23H2,1H3;1H;/q-1;;+2/p-1/t29-,30-;;/m0../s1
InChI key	MDABGVLQRDDWLY-ARDORAJISA-M

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable