半岛bd体育手机客户端 说明

一般描述

SnAP (Sn amino protocol) reagents have been developed by the Bode group. SnAP reagents are air and moisture stable. They can be prepared from simple reactions with cheap raw materials. SnAP 2-Spiro-(4-Pip) M, also referred to as SnAP 2-spiro-(4-piperdine) morpholine, is a regioisomeric SnAP reagent. This reagent can be prepared fromN-Boc piperidone.

应用

SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturatedN-heterocycles. The synthesis ofN-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group
SnAP TM Reagent may be used to synthesize 3-substituted thiomorpholines from aldehydes. It may also be used in the preparation of unprotected, saturated N-heterocyclic compounds.

包装

1 g in glass bottle

其他说明

Technology spotlight: SnAP Reagents
Professor product portal: Jeffrey Bode Research Group
SnAP Reagents for the Synthesis of Piperazines and Morpholines
SnAP reagents for the one-step synthesis of medium-ring saturatedN-heterocycles from aldehydes
SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of SaturatedN-Heterocycles
Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic SaturatedN-Heterocycles

基本信息

经验(实验)分子式	C15H35NSSn
分子量	380.22
MDL编号	MFCD23703162
PubChem化学物质编号	329768678
NACRES	NA.22

半岛bd体育手机客户端 性质

形式	liquid
质量水平	100
折射率	n /D 1.512
密度	1.158 at 25 ℃
储存温度	?20℃
SMILES string	CCCC[Sn](CCCC)(CSCCN)CCCC
InChI	1S/3C4H9.C3H8NS.Sn/c3*1-3-4-2;1-5-3-2-4;/h3*1,3-4H2,2H3;1-4H2;
InChI key	DYBMHPJDHUKXRF-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H301 + H311 + H331 - H315 - H319 - H335 - H410
预防措施声明	P273 - P280 - P301 + P310 + P330 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338
危险分类	Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable