半岛bd体育手机客户端 说明
应用
The CLAmP (Carbonyl LinchpinN,O-dimethylhydroxylamine pyrrole) reagent, reported by Sarpong and Heller, is a useful building block for the efficient synthesis of unsymmetrical ketones. CLAmP shows high versatility based on compatibility with both highly reactive, thermally unstable nucleophiles as well as less reactive stable nucleophiles. It reacts with Grignard reagents to form the corresponding Weinreb amides.
包装
1 g in glass bottle
其他说明
One-pot Unsymmetrical Ketone Synthesis Employing a Pyrrole-Bearing Formal Carbonyl Dication Linchpin Reagent
基本信息
| 经验(实验)分子式 | C7H10N2O2 |
| 分子量 | 154.17 |
| PubChem化学物质编号 | 329769111 |
半岛bd体育手机客户端 性质
| 形式 | liquid |
| 质量水平 | 100 |
| 折射率 | n
|
| 密度 | 1.126 g/mL |
| 储存温度 | 2-8℃ |
| SMILES string | O=C(N(OC)C)N1C=CC=C1 |
| InChI | 1S/C7H10N2O2/c1-8(11-2)7(10)9-5-3-4-6-9/h3-6H,1-2H3 |
| InChI key | NLSJGNBOCVXWHS-UHFFFAOYSA-N |
安全信息
| 储存分类代码 | 10 - Combustible liquids |
| WGK | WGK 3 |
| 闪点(F) | 230.0 °F |
| 闪点(C) | 110 ℃ |
Sigma-Aldrich
m.cnreagent.com
