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Tris(3,5-dimethylphenyl)phosphine

三(3,5-二甲苯基)膦

品牌
Sigma-Aldrich
CAS
69227-47-0
货号
698253
包装型号
规格纯度
96%
价格
946.06 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
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半岛bd体育手机客户端 名称:
69227-47-0
Tris(3,5-dimethylphenyl)phosphine
Tri-3,5-xylylphosphine
三(3,5-二甲苯基)膦
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

应用

Catalyst for:

  • Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones
  • Highly selective rhodium-catalyzed hydrogenation reactions
  • Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes

Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes

Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis

包装

1 g in glass bottle

基本信息

线性分子式 [(CH3)2C6H3]3P
分子量 346.44
MDL编号 MFCD03094579
PubChem化学物质编号 329761997
NACRES NA.22

半岛bd体育手机客户端 性质

质量水平 100
测定 96%
reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp 160-165 ℃
官能团 phosphine
SMILES string Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3cc(C)cc(C)c3
InChI 1S/C24H27P/c1-16-7-17(2)11-22(10-16)25(23-12-18(3)8-19(4)13-23)24-14-20(5)9-21(6)15-24/h7-15H,1-6H3
InChI key XRALRSQLQXKXKP-UHFFFAOYSA-N

安全信息

象形图 GHS07
警示用语: Warning
危险声明 H302
危险分类 Acute Tox. 4 Oral
储存分类代码 13 - Non Combustible Solids
WGK WGK 3
闪点(F) Not applicable
闪点(C) Not applicable
个人防护装备 dust mask type N95 (US), Eyeshields, Gloves

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