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Boric anhydride

三氧化二硼

品牌
Sigma-Aldrich
CAS
1303-86-2
货号
15678
规格纯度
puriss. p.a., ≥98% (T)
价格
511.44 *本价格含增值税费
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半岛bd体育手机客户端 名称:
1303-86-2
Boric anhydride
Boron trioxide
硼酸酐
三氧化二硼
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

一般描述

Boric anhydride (Boron trioxide) is a colorless glassy hygroscopic mass having rhombic crystals. Its dissolution in water is a highly exothermic reaction and orthoboric acid is formed. It can be prepared by heating boric acid. It is used as flux in metallurgical processes. It has been reported as an inhibitor of crystallization.

应用

Boric anhydride can be used as a boron precursor to synthesize:

  • Boron carbon nitride nanosheet (BCN) by thermal condensation reaction with urea and melamine.
  • Boron-doped reduced graphene oxide (B-rGO) via a chemical vapor deposition method.
It can also be used as an additive along with pinacol to synthesize 4-alkoxy-5-hydroxy-2-pentenoate derivatives by Pd-catalyzed reaction of α, β-unsaturated γ, δ-epoxy esters with various alcohols.

其他说明

通过熔融作用分解硅酸盐的试剂

基本信息

经验(实验)分子式 B2O3
分子量 69.62
EC 号 215-125-8
MDL编号 MFCD00011315
PubChem化学物质编号 57647516
NACRES NA.21

半岛bd体育手机客户端 性质

质量水平 100
蒸汽密度 >1 (vs air)
等级 puriss. p.a.
测定 ≥98% (T)
缺失 ≤3% loss on ignition, 900 ℃
mp 450 ℃ (lit.)
密度 2.46 g/mL at 25 ℃ (lit.)
痕量阴离子 chloride (Cl-): ≤20 mg/kg
sulfate (SO42-): ≤50 mg/kg
痕量阳离子 Ag: ≤5 mg/kg
Al: ≤50 mg/kg
Ba: ≤5 mg/kg
Bi: ≤5 mg/kg
Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
K: ≤30 mg/kg
Mg: ≤20 mg/kg
Mn: ≤5 mg/kg
Mo: ≤5 mg/kg
Na: ≤200 mg/kg
Ni: ≤5 mg/kg
Pb: ≤30 mg/kg
Sr: ≤5 mg/kg
Tl: ≤10 mg/kg
Zn: ≤5 mg/kg
SMILES string O=BOB=O
InChI 1S/B2O3/c3-1-5-2-4
InChI key JKWMSGQKBLHBQQ-UHFFFAOYSA-N

安全信息

象形图 GHS08
警示用语: Danger
危险声明 H360D
预防措施声明 P201 - P202 - P280 - P308 + P313 - P405 - P501
危险分类 Repr. 1B
储存分类代码 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK WGK 1
闪点(F) Not applicable
闪点(C) Not applicable
个人防护装备 dust mask type N95 (US), Eyeshields, Gloves

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