半岛bd体育手机客户端 说明
应用
(S)-(-)-2′-Amino-1,1′-binaphthalen-2-ol or (S)-NOBIN, is a non-symmetrically substituted 1,1′-binaphthalene ligand. It can be used as a catalyst in the asymmetric synthesis of unnatural α-alkyl amino acids by phase-transfer catalysis (PTC). (S)-NOBIN can also be employed as starting material to prepareN-monoalkyl andN,N-dialkyl (S)-NOBIN analogs by reacting with aldehydes via reductive amination reaction.N-monoaryl derivatives are obtained from NOBIN via Hartwig?Buchwald arylation reaction.
包装
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.
基本信息
| 经验(实验)分子式 | C20H15NO |
| 分子量 | 285.34 |
| MDL编号 | MFCD01882346 |
| PubChem化学物质编号 | 329763211 |
| NACRES | NA.22 |
半岛bd体育手机客户端 性质
| 质量水平 | 100 |
| 测定 | ≥96.5% (HPLC) 97% |
| 光学纯度 | enantiomeric excess: ≥98.0% |
| InChI | 1S/C20H15NO/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12,22H,21H2 |
| InChI key | HIXQCPGXQVQHJP-UHFFFAOYSA-N |
安全信息
| 象形图 |   |
| 警示用语： | Danger |
| 危险声明 | H318 - H410 |
| 预防措施声明 | P273 - P280 - P305 + P351 + P338 - P501 |
| 危险分类 | Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 |
| 储存分类代码 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
Sigma-Aldrich
m.cnreagent.com
