半岛bd体育手机客户端 说明
一般描述
cis-1,4-Diacetoxy-2-butene is an ester. Ruthenium olefin metathesis catalysts having cyclic (alkyl)(amino)carbenes effectively catalyzes the cross-metathesis ofcis-1,4-diacetoxy-2-butene with allylbenzene.cis-1,4-Diacetoxy-2-butene on pyrolysis affords 1-acetoxy-1,3-butadiene, a diacetate and an isomeric 1,2-diacetoxy-3-butene. Mechanism of pyrolysis has been investigated.
应用
cis-1,4-Diacetoxy-2-butene may be used in the preparation of hindered Diels-Alder adducts. It may be used for the synthesis of 1,2,3,4-tetrahydro-2-vinylquinoxalines, via Palladium-catalyzed tandem allylation of 1,2-phenylenediamines.
包装
25 mL in glass bottle
基本信息
| 线性分子式 | CH3CO2CH2CH=CHCH2O2CCH3 |
| 分子量 | 172.18 |
| MDL编号 | MFCD00059339 |
| PubChem化学物质编号 | 24870459 |
| NACRES | NA.22 |
半岛bd体育手机客户端 性质
| 质量水平 | 100 |
| 测定 | 95% |
| 折射率 | n
|
| bp | 120-121 ℃/18 mmHg (lit.) |
| 密度 | 1.08 g/mL at 25 ℃ (lit.) |
| SMILES string | [H]\C(COC(C)=O)=C(/[H])COC(C)=O |
| InChI | 1S/C8H12O4/c1-7(9)11-5-3-4-6-12-8(2)10/h3-4H,5-6H2,1-2H3/b4-3- |
| InChI key | VZUAUHWZIKOMFC-ARJAWSKDSA-N |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H315 |
| 危险分类 | Skin Irrit. 2 |
| 储存分类代码 | 10 - Combustible liquids |
| WGK | WGK 3 |
| 闪点(F) | 235.4 °F - closed cup |
| 闪点(C) | 113 ℃ - closed cup |
| 个人防护装备 | Eyeshields, Gloves, type ABEK (EN14387) respirator filter |
Sigma-Aldrich
m.cnreagent.com
